3-氯苯甲醛

3-氯苯甲醛
别名	间氯苯甲醛
识别
CAS号	587-04-2
性质
化学式	C7H5ClO
摩尔质量	140.57 g·mol−1
熔点	17—18 °C（290—291 K）
沸点	213—215 °C（486—488 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

3-氯苯甲醛是一种有机化合物，化学式为ClC₆H₄CHO，是氯苯甲醛的同分异构体之一。它可由3-氯苯甲醇的氧化反应制得。^[3]^[4]^[5]它进一步氧化可以得到3-氯苯甲酸。^[6]它和丙二腈反应，可以得到3-氯亚苄基丙二腈。^[7]

参考文献

^ Yongfei Wang, Hongbin Zhao, Zhizhi Hu, Masaru Kimura, Zhang Zhiqiang, Lei Peng, Koji Hiratsuka. A Convenient Formylation of 2-(Dibromomethyl)-6,11-diphenyl-5,12-naphthacenequinone Using N,N-Dimethylformamide or N,N-Dimethylacetamide: Synthesis of 2-Formyl Rubrene. Synthesis. 2011-01, 2011 (02): 287–291 [2021-06-12]. ISSN 0039-7881. doi:10.1055/s-0030-1258362. （原始内容存档于2018-06-04）（英语）.
^ Mahmood Tajbakhsh, Setareh Habibzadeh. Cleavage of C=N derivatives and Oxidation of Thiols in Water under Neutral Conditions with 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bischloride. Journal of Chemical Research. 2007-08, 2007 (8): 486–489 [2021-06-12]. ISSN 1747-5198. doi:10.3184/030823407X240890 （英语）.
^ Babak Karimi, Farhad Kabiri Esfahani. Gold Nanoparticles Supported on the Periodic Mesoporous Organosilicas as Efficient and Reusable Catalyst for Room Temperature Aerobic Oxidation of Alcohols. Advanced Synthesis & Catalysis. 2012-05-07, 354 (7): 1319–1326 [2021-06-12]. doi:10.1002/adsc.201100802 （英语）.
^ Takeshi Nishiguchi, Fumi Asano. Oxidation of alcohols by metallic nitrates supported on silica gel. The Journal of Organic Chemistry. 1989-03, 54 (7): 1531–1535 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo00268a011 （英语）.
^ Katsuhiko Moriyama, Misato Takemura, Hideo Togo. Selective Oxidation of Alcohols with Alkali Metal Bromides as Bromide Catalysts: Experimental Study of the Reaction Mechanism. The Journal of Organic Chemistry. 2014-07-03, 79 (13): 6094–6104 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo5008064. （原始内容存档于2022-04-25）（英语）.
^ Mahdi Hajimohammadi, Zahra Ahmadi Khamesi, Parisa Nosrati. Efficient aerobic photooxygenation of aldehydes to carboxylic acids using cobalt(II) phthalocyanine sulfonate as a photosensitizer in organic-water biphasic media. Transition Metal Chemistry. 2019-02, 44 (2): 167–173 [2021-06-12]. ISSN 0340-4285. doi:10.1007/s11243-018-0281-x （英语）.
^ Biswajit Laha, Sadhika Khullar, Alisha Gogia, Sanjay K. Mandal. Effecting structural diversity in a series of Co( ii )–organic frameworks by the interplay between rigidity of a dicarboxylate and flexibility of bis(tridentate) spanning ligands. Dalton Transactions. 2020, 49 (35): 12298–12310 [2021-06-12]. ISSN 1477-9226. doi:10.1039/D0DT02153A （英语）.

[1] Yongfei Wang, Hongbin Zhao, Zhizhi Hu, Masaru Kimura, Zhang Zhiqiang, Lei Peng, Koji Hiratsuka. A Convenient Formylation of 2-(Dibromomethyl)-6,11-diphenyl-5,12-naphthacenequinone Using N,N-Dimethylformamide or N,N-Dimethylacetamide: Synthesis of 2-Formyl Rubrene. Synthesis. 2011-01, 2011 (02): 287–291 [2021-06-12]. ISSN 0039-7881. doi:10.1055/s-0030-1258362. （原始内容存档于2018-06-04）（英语）.

[2] Mahmood Tajbakhsh, Setareh Habibzadeh. Cleavage of C=N derivatives and Oxidation of Thiols in Water under Neutral Conditions with 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bischloride. Journal of Chemical Research. 2007-08, 2007 (8): 486–489 [2021-06-12]. ISSN 1747-5198. doi:10.3184/030823407X240890 （英语）.

[3] Babak Karimi, Farhad Kabiri Esfahani. Gold Nanoparticles Supported on the Periodic Mesoporous Organosilicas as Efficient and Reusable Catalyst for Room Temperature Aerobic Oxidation of Alcohols. Advanced Synthesis & Catalysis. 2012-05-07, 354 (7): 1319–1326 [2021-06-12]. doi:10.1002/adsc.201100802 （英语）.

[4] Takeshi Nishiguchi, Fumi Asano. Oxidation of alcohols by metallic nitrates supported on silica gel. The Journal of Organic Chemistry. 1989-03, 54 (7): 1531–1535 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo00268a011 （英语）.

[5] Katsuhiko Moriyama, Misato Takemura, Hideo Togo. Selective Oxidation of Alcohols with Alkali Metal Bromides as Bromide Catalysts: Experimental Study of the Reaction Mechanism. The Journal of Organic Chemistry. 2014-07-03, 79 (13): 6094–6104 [2021-06-12]. ISSN 0022-3263. doi:10.1021/jo5008064. （原始内容存档于2022-04-25）（英语）.

[6] Mahdi Hajimohammadi, Zahra Ahmadi Khamesi, Parisa Nosrati. Efficient aerobic photooxygenation of aldehydes to carboxylic acids using cobalt(II) phthalocyanine sulfonate as a photosensitizer in organic-water biphasic media. Transition Metal Chemistry. 2019-02, 44 (2): 167–173 [2021-06-12]. ISSN 0340-4285. doi:10.1007/s11243-018-0281-x （英语）.

[7] Biswajit Laha, Sadhika Khullar, Alisha Gogia, Sanjay K. Mandal. Effecting structural diversity in a series of Co( ii )–organic frameworks by the interplay between rigidity of a dicarboxylate and flexibility of bis(tridentate) spanning ligands. Dalton Transactions. 2020, 49 (35): 12298–12310 [2021-06-12]. ISSN 1477-9226. doi:10.1039/D0DT02153A （英语）.

[3]

[4]

[5]

[6]

[7]

[1]

[2]