亞磷酸酯
亞磷酸酯(英語:Phosphite ester)是指亞磷酸(HP(O)(OH)2)或其互變異構體(P(OH)3)與醇形成的酯,常見的有亞磷酸二甲酯(HOP(OCH3)2)[1]和亞磷酸三甲酯(P(OCH3)3)[2]。
![](http://upload.wikimedia.org/wikipedia/commons/thumb/5/58/Phosphite.svg/250px-Phosphite.svg.png)
製備
編輯參考文獻
編輯- ^ Balint, Erika; Tajti, Adam; Drahos, Laszlo; Ilia, Gheorge; Keglevich, Gyorgy. Alcoholysis of Dialkyl Phosphites Under Microwave Conditions. Current Organic Chemistry. 2013, 17: 555–562.
- ^ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014: 931. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069-FP001.
- ^ Malowan, John E. Diethyl phosphite. Inorganic Syntheses. Inorganic Syntheses 4. 1953: 58–60. ISBN 9780470132357. doi:10.1002/9780470132357.ch19.
- ^ Hoffmann, Friedrich W.; Ess, Richard J.; Usingef, Robert P. The Transesterification of Trialkyl Phosphites with Aliphatic Alcohols. Journal of the American Chemical Society. November 1956, 78 (22): 5817–5821. doi:10.1021/ja01603a026.