六氰合鈷(III)酸鎳(II)

六氰合鈷(III)酸鎳(II)
識別
CAS號	14074-48-7
性質
化學式	Ni3[Co(CN)6]2
摩爾質量	606.161 g·mol⁻¹
外觀	淺藍色固體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

六氰合鈷(III)酸鎳(II)是一種無機化合物，化學式為Ni₃[Co(CN)₆]₂。它可由六氰合鈷(III)酸鉀和氯化鎳^[1]、硫酸鎳^[2]或硝酸鎳^[3]反應，經過濾、洗滌後得到。一些文獻在製備時會加入檸檬酸鈉。^[1]^[4]該配合物它在高溫下可以分解。^[5]它可用於製備(Ni,Co)Se₂納米材料。^[4]

參考文獻

^ ^1.0 ^1.1 ^1.2 Gang Huang, Dongming Yin, Feifei Zhang, Qian Li, Limin Wang. Yolk@Shell or Concave Cubic NiO–Co 3 O 4 @C Nanocomposites Derived from Metal–Organic Frameworks for Advanced Lithium-Ion Battery Anodes. Inorganic Chemistry. 2017-08-21, 56 (16): 9794–9801 [2019-06-25]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b01296 （英語）.
^ E. Reguera, E. Marín, A. Calderón, J. Rodríguez-Hernández. Photo-induced charge transfer in Prussian blue analogues as detected by photoacoustic spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007-09, 68 (1): 191–197 [2019-06-25]. doi:10.1016/j.saa.2006.11.013. （原始內容存檔於2018-06-28）（英語）.
^ Satish K. Nune, Praveen K. Thallapally, Benard Peter McGrail, Harsha V. R. Annapureddy, Liem X. Dang, Donghai Mei, Naveen Karri, Kyle J. Alvine, Matthew J. Olszta, Bruce W. Arey, Alice Dohnalkova. Adsorption Kinetics in Nanoscale Porous Coordination Polymers. ACS Applied Materials & Interfaces. 2015-10-07, 7 (39): 21712–21716 [2019-06-25]. ISSN 1944-8244. doi:10.1021/acsami.5b04109 （英語）.
^ ^4.0 ^4.1 Xun Xu, Hanfeng Liang, Fangwang Ming, Zhengbing Qi, Yaqiang Xie, Zhoucheng Wang. Prussian Blue Analogues Derived Penroseite (Ni,Co)Se 2 Nanocages Anchored on 3D Graphene Aerogel for Efficient Water Splitting. ACS Catalysis. 2017-09, 7 (9): 6394–6399 [2019-06-25]. ISSN 2155-5435. doi:10.1021/acscatal.7b02079 （英語）.
^ Tribunescu, P.; Pirlea, Gh. Kinetics of the thermal decomposition of cobalt and nickel hexacyanocobaltates and mixed cobalt-thallium and nickel-thallium hexacyanocobaltates（羅馬尼亞文）. Buletinul Stiintific si Tehnic al Institutului Politehnic Traian Vuia Timisoara, 1969. 14 (2): 561-567. ISSN: 0563-5594.

[Huang-1] 1.0 ^1.1 ^1.2 Gang Huang, Dongming Yin, Feifei Zhang, Qian Li, Limin Wang. Yolk@Shell or Concave Cubic NiO–Co 3 O 4 @C Nanocomposites Derived from Metal–Organic Frameworks for Advanced Lithium-Ion Battery Anodes. Inorganic Chemistry. 2017-08-21, 56 (16): 9794–9801 [2019-06-25]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b01296 （英語）.

[2] E. Reguera, E. Marín, A. Calderón, J. Rodríguez-Hernández. Photo-induced charge transfer in Prussian blue analogues as detected by photoacoustic spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007-09, 68 (1): 191–197 [2019-06-25]. doi:10.1016/j.saa.2006.11.013. （原始內容存檔於2018-06-28）（英語）.

[3] Satish K. Nune, Praveen K. Thallapally, Benard Peter McGrail, Harsha V. R. Annapureddy, Liem X. Dang, Donghai Mei, Naveen Karri, Kyle J. Alvine, Matthew J. Olszta, Bruce W. Arey, Alice Dohnalkova. Adsorption Kinetics in Nanoscale Porous Coordination Polymers. ACS Applied Materials & Interfaces. 2015-10-07, 7 (39): 21712–21716 [2019-06-25]. ISSN 1944-8244. doi:10.1021/acsami.5b04109 （英語）.

[Xu-4] 4.0 ^4.1 Xun Xu, Hanfeng Liang, Fangwang Ming, Zhengbing Qi, Yaqiang Xie, Zhoucheng Wang. Prussian Blue Analogues Derived Penroseite (Ni,Co)Se 2 Nanocages Anchored on 3D Graphene Aerogel for Efficient Water Splitting. ACS Catalysis. 2017-09, 7 (9): 6394–6399 [2019-06-25]. ISSN 2155-5435. doi:10.1021/acscatal.7b02079 （英語）.

[5] Tribunescu, P.; Pirlea, Gh. Kinetics of the thermal decomposition of cobalt and nickel hexacyanocobaltates and mixed cobalt-thallium and nickel-thallium hexacyanocobaltates（羅馬尼亞文）. Buletinul Stiintific si Tehnic al Institutului Politehnic Traian Vuia Timisoara, 1969. 14 (2): 561-567. ISSN: 0563-5594.

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