拉脹材料
拉脹材料(Auxetics)也稱為負泊松比材料,是泊松比為負值的結構或材料[1]。一般材料在拉伸時,垂直於拉伸方向的部份會收縮。但拉脹材料在拉伸時,垂直拉伸方向的部份會膨脹,這是因為其特殊內部構造,以及在單軸施力下的形變方式有關。拉脹材料可能是單分子、晶體,或是特別的巨觀結構。
有拉脹特性的材料及結構多半會有高吸震及高斷裂抵抗的能力。拉脹材料可用在像防彈背心[2]、包裝材料、護膝及護肘、強健吸震材料及膠棉拖把。
歷史
編輯auxetic一詞源自希臘文的αὐξητικός(auxetikos),意思是「傾向於增加」。這個詞是由艾希特大學的Ken Evans教授所創[3][4]。
由柏林的研究者K. Pietsch在1978年發明的RFS結構(鑽石摺疊結構),是首批人工合成的拉脹材料之一[5],K. Pietsch沒有使用auxetic一詞,不過他第一個描述其底層的槓桿特性以及其非線性的力學特性,因此視為是拉脹網狀材料的發明者。 最早發表的負泊松常數論文是由A. G. Kolpakov在1985年提出《確認彈性網路的平均特性》(Determination of the average characteristics of elastic frameworks)。下一個有關合成拉脹材料的論文是在1987年的《科學》期刊,標題是《負泊松比的泡沬結構》(Foam structures with a Negative Poisson's Ratio)[6],是威斯康星大學麥迪遜分校的R.S. Lakes所提出。auxetic一詞的使用大約是在1991年開始[7]。在1985年開始發表用週期性凹六邊形單元(有負泊松比特性)建構複合結構的設計[8][9][10][11]。
特性
編輯一般而言,拉脹材料是低密度的物質,因此其中允許有類似槓桿,可以變形的拉脹微結構[12]。
巨觀下,拉脹特性可以用非彈性的弦繞在彈性的繩子上來說明。當結構的末端受力拉開時,非彈性的弦伸直,彈性繩伸展並繞在其周圍,因此增加了結構的有效體積。巨觀下的拉脹特性也可以用來開發有強化機能的產品,例如由Grima及Evans開發,以拉脹可旋轉三角形結構為基礎的鞋子[13][14][15]
常見的拉脹材料
編輯以下一些拉脹材料的例子:
- 拉脹聚氨酯泡沫[16][17]。
- α-方矽石[18]。
- 特定的岩石及礦物[19]。
- 石墨烯,可以透過引入晶格空位使其有拉脹性[20][21]。
- 活的動物骨骼組織(這個只是推測)[19]。
- 在正常運動範圍內的肌腱[22]。
- 特殊的聚四氟乙烯聚合物,例如Gore-Tex[23]。
- 一些特殊的紙張。若紙張在平行紙面的方向受力拉伸,由於其網狀的結構,其厚度也會增加[24][25]
- 一些摺紙形成的結構,例如鑽石摺疊結構(Diamond-Folding-Structure、也簡稱為RFS)、人字紋摺疊結構(FFS)或是三浦摺疊[26][27],或是由這些摺疊衍生的週期性圖案[28][29]。
- 一些為呈現負泊松比而設計的特製結構[30][31]。
- 鏈狀有機分子。近期的研究發現像是n-烷烴或是類似結構的有機晶體可能會有拉脹特性[32]。
- 加工過的針刺不織布。因為其纖維的網狀結構,應用熱和壓力的加工方案可以讓不織布具有拉脹特性[33][34]。
相關條目
編輯參考資料
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- ^ Quinion, Michael, Auxetic, 1996-11-09 [2009-01-02], (原始內容存檔於2009-02-17).
- ^ Evans, Ken, Auxetic polymers: a new range of materials., Endeavour, 1991, 15 (4): 170–174, doi:10.1016/0160-9327(91)90123-S.
- ^ RFS-Struktur (Rauten-Falt-Struktur) (頁面存檔備份,存於網際網路檔案館), In: Materialblog.de
- ^ Lakes, R.S., Foam structures with a negative Poisson's ratio, Science, 1987-02-27, 235 (4792): 1038–40, Bibcode:1987Sci...235.1038L, PMID 17782252, doi:10.1126/science.235.4792.1038.
- ^ Evans, Ken, Auxetic polymers: a new range of materials, Endeavour, 1991, 15 (4): 170–174, doi:10.1016/0160-9327(91)90123-S.
- ^ Kolpakov, A.G. Determination of the average characteristics of elastic frameworks. Journal of Applied Mathematics and Mechanics. 1985, 49 (6): 739–745. Bibcode:1985JApMM..49..739K. doi:10.1016/0021-8928(85)90011-5.
- ^ Almgren, R.F. An isotropic three-dimensional structure with Poisson's ratio=-1. Journal of Elasticity. 1985, 15 (4): 427–430. doi:10.1007/bf00042531.
- ^ Theocaris, P.S.; Stavroulakis, G.E.; Panagiotopoulos, P.D. Negative Poisson's ratio in composites with star-shaped inclusions: a numerical homogenization approach .. Archive of Applied Mechanics. 1997, 67 (4): 274–286. Bibcode:1997AAM....67..274T. doi:10.1007/s004190050117.
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