磷化鐠

磷化鐠
別名	Phosphanylidynepraseodymium
識別
CAS號	12066-49-8
PubChem	82904
ChemSpider	74805
SMILES	P#[Pr];
EINECS	235-068-2
性質
化學式	PPr
摩爾質量	171.88 g·mol−1
外觀	深綠色晶體
密度	g/cm3
溶解性（水）	在水中分解
結構
晶體結構	立方
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

磷化鐠是鐠和磷的無機化合物，化學式為PrP。^[2]^[3]^[4]該化合物會結晶。

合成

在碘蒸汽下將鐠金屬和磷共熱：^[5]

{\ce {Pr + P -> PrP}}

物理性質

磷化鐠會形成立方晶體，空間群為F m3m，晶格常數為a = 0.5872 nm，Z = 4，結構類似氯化鈉NaCl。^[6]^[7]

這個化合物在3120 °C均勻融化。

參考文獻

^ Rowley, Adrian T.; Parkin, Ivan P. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry (Royal Society of Chemistry (RSC)). 1993, 3 (7): 689. ISSN 0959-9428. doi:10.1039/jm9930300689.
^ Praseodymium Phosphide. American Elements. [14 December 2021]. （原始內容存檔於2021-12-14）（英語）.
^ Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. 1980: 252 [14 December 2021] （英語）.
^ O'Bannon, Loran. Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. 6 December 2012: 199 [14 December 2021]. ISBN 978-1-4613-2655-7 （英語）.
^ Mironov, K. E. A transport reaction for the growth of praseodymium phospide. Journal of Crystal Growth. 1 January 1968, 3–4: 150–152 [14 December 2021]. Bibcode:1968JCrGr...3..150M. doi:10.1016/0022-0248(68)90115-2 （英語）.
^ Nowacki, J. D. H. Donnay, and Werner. Crystal Data: Classification of Substances by Space Groups and their Identification from Cell Dimensions. Geological Society of America. 1954: 509 [14 December 2021]. ISBN 978-0-8137-1060-0 （英語）.
^ Yaduvanshi, Namrata; Singh, Sadhna. Exploration of pressure induced phase transition in praseodymium phosphide (PrP) with the NaCl-type structure. Dae Solid State Physics Symposium 2017. AIP Conference Proceedings 1942 (1): 030001. 10 April 2018 [14 December 2021]. Bibcode:2018AIPC.1942c0001Y. doi:10.1063/1.5028582. （原始內容存檔於2021-12-14）.

[1] Rowley, Adrian T.; Parkin, Ivan P. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry (Royal Society of Chemistry (RSC)). 1993, 3 (7): 689. ISSN 0959-9428. doi:10.1039/jm9930300689.

[2] Praseodymium Phosphide. American Elements. [14 December 2021]. （原始內容存檔於2021-12-14）（英語）.

[3] Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. 1980: 252 [14 December 2021] （英語）.

[4] O'Bannon, Loran. Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. 6 December 2012: 199 [14 December 2021]. ISBN 978-1-4613-2655-7 （英語）.

[5] Mironov, K. E. A transport reaction for the growth of praseodymium phospide. Journal of Crystal Growth. 1 January 1968, 3–4: 150–152 [14 December 2021]. Bibcode:1968JCrGr...3..150M. doi:10.1016/0022-0248(68)90115-2 （英語）.

[6] Nowacki, J. D. H. Donnay, and Werner. Crystal Data: Classification of Substances by Space Groups and their Identification from Cell Dimensions. Geological Society of America. 1954: 509 [14 December 2021]. ISBN 978-0-8137-1060-0 （英語）.

[7] Yaduvanshi, Namrata; Singh, Sadhna. Exploration of pressure induced phase transition in praseodymium phosphide (PrP) with the NaCl-type structure. Dae Solid State Physics Symposium 2017. AIP Conference Proceedings 1942 (1): 030001. 10 April 2018 [14 December 2021]. Bibcode:2018AIPC.1942c0001Y. doi:10.1063/1.5028582. （原始內容存檔於2021-12-14）.

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