1,3-二乙烯基苯
1,3-二乙烯基苯是一種有機化合物，化學式為C10H10。它可由1,3-二碘苯和四乙烯基硅在鈀催化下反應得到。[2]1,3-苯二甲醛和三苯基甲基溴化鏻在叔丁醇鉀的存在下反應，也能得到1,3-二乙烯基苯。[3]它和溴反應，根據反應條件不同，可以得到1,5-二溴-2,4-二乙烯基苯[4]或1,3-二(1,2-二溴乙基)苯[5]。它和苯甲酰胺、氫氧化鉀在二甲基亞碸中於120 °C反應，可以得到N,N'-(1,3-苯二亞基-2,1-乙二基)二苯甲酰胺。[6]
| 1,3-二乙烯基苯 | |
|---|---|
| |
| 識別 | |
| CAS號 | 108-57-6 
|
| 性質 | |
| 化學式 | C10H10 |
| 摩爾質量 | 130.19 g·mol−1 |
| 熔點 | −52.3 °C（220.8 K）[1] |
| 沸點 | 121 °C（394 K）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-30].
- ^ Abdessamad Grirrane, Hermenegildo Garcia, Avelino Corma. Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C–C coupling of vinylsilanes and halobenzenes leading to styrenes. Journal of Catalysis. 2013-06, 302: 49–57 [2021-06-30]. doi:10.1016/j.jcat.2013.02.019. （原始內容存檔於2018-06-11） （英語）.
- ^ Shunsuke Tanaka, Masayoshi Matsumoto, Raita Goseki, Takashi Ishizone, Akira Hirao. Living Anionic Polymerization of 1,4-Divinylbenzene and Its Isomers. Macromolecules. 2013-01-08, 46 (1): 146–154 [2021-06-30]. ISSN 0024-9297. doi:10.1021/ma302246u （英語）.
- ^ Cui, Aijun; Tian, Junkai; Liu, Liu; Li, Jing; Chen, Qun; He, Mingyang. Preparation of 1,3-divinyl-4,6-benzenedicarboxylic acid oxygen absorbents for oxygen-absorbing polyester. 2012. CN 102746496 A.
- ^ Mitchell, Reginald H.; Ghose, Bhupendra N.; Williams, Mary E. The intra- and intermolecular copper (I) catalyzed couplings of vinyl Grignards. A facile synthesis of pleiadiene and a synthesis of a conjugated 14-membered ring system. Canadian Journal of Chemistry. 1977, 55 (2): 210–219. ISSN 0008-4042. doi:10.1139/v77-035.
- ^ Ayushee, Monika Patel, Priyanka Meena, Kousar Jahan, Prasad V. Bharatam, Akhilesh K. Verma. Base-Mediated Anti-Markovnikov Hydroamidation of Vinyl Arenes with Arylamides. Organic Letters. 2021-01-15, 23 (2): 565–570 [2021-06-30]. ISSN 1523-7060. doi:10.1021/acs.orglett.0c04084 （英語）.