三氟甲硒醇四甲基銨

三氟甲硒醇四甲基銨是一種化合物,化學式為[(CH3)4N]SeCF3,它可由四甲基氟化銨和SeCF2反應製得。[2]四甲基氟化銨、三甲基三氟甲基矽烷紅硒的反應也能製得標題化合物。[1]它和(TDAE)Br2(TDAE為四(二甲氨基)乙烯)反應,可以得到(TDAE)(SeCF3)2[3]它和氟硼酸銀氯化亞金反應,可以得到[M(SeCF3)2](M=Ag或Au)配合物。[4]它可用於有機物的三氟甲硒基化反應。[5]

三氟甲硒醇四甲基銨
識別
CAS號 75264-92-5  checkY
SMILES
 
  • FC(F)(F)[Se-].C[N+](C)(C)C
性質
外觀 無色固體[1]
熔點 215—217 °C(488—490 K)(分解)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ 1.0 1.1 1.2 Wieland Tyrra, Dieter Naumann, Yurii L Yagupolskii. Stable trifluoromethylselenates(0), [A]SeCF3—synthesis, characterizations and properties. Journal of Fluorine Chemistry. 2003-10, 123 (2): 183–187 [2020-04-30]. doi:10.1016/S0022-1139(03)00118-0. (原始內容存檔於2018-06-25) (英語). 
  2. ^ Darmadi, Alexius; Haas, Alois; Koch, Bernd. Simplified synthesis and reactors of selenocarbonyl difluoride. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1980. 35B (5): 526-529. ISSN: 0340-5087
  3. ^ Tyrra, Wieland; Naumann, Dieter; Pohl, Herbert; Pantenburg, Ingo. Trifluoromethylselenate(0), [SeCF3]-, and trifluoromethyltellurate(0), [TeCF3]- - crystalline products of the reduction of the bis(trifluoromethyl)​dichalcogen compounds, E2(CF3)​2 (E = Se, Te), with tetrakis(dimethylamino)​ethene (TDAE). Zeitschrift fuer Anorganische und Allgemeine Chemie, 2003. 629 (6): 1039-1043. ISSN: 0044-2313
  4. ^ Dieter Naumann, Wieland Tyrra, Silke Quadt, Sigrid Buslei, Ingo Pantenburg, Mathias Schäfer. Bis(trifluoromethylselenato(0))metallates(I) of Silver and Gold, [M(SeCF3)2]− (M = Ag, Au). Zeitschrift für anorganische und allgemeine Chemie. 2005-10, 631 (13-14): 2733–2737 [2020-04-30]. ISSN 0044-2313. doi:10.1002/zaac.200500115 (德語). 
  5. ^ Qiu-Yan Han, Cheng-Long Zhao, Tao Dong, Jin Shi, Kai-Li Tan, Cheng-Pan Zhang. Metal-free oxidative trifluoromethylselenolation of electron-rich (hetero)arenes with the readily available [Me 4 N][SeCF 3 ] reagent. Organic Chemistry Frontiers. 2019, 6 (15): 2732–2737 [2020-04-30]. ISSN 2052-4129. doi:10.1039/C9QO00631A (英語).