十四烷基三己基癸酸鏻
十四烷基三己基癸酸鏻是一種季鏻鹽，化學式為[(C6H13)3PC14H29]+CH3(CH2)8COO−。它可由十四烷基三己基氯化鏻和癸酸在氫氧化鈉的存在下於水中反應得到。[2]癸酸和相應的氫氧化鏻在乙醇中反應，也能得到產物。[3]它可作為溶劑，溶解硫、硒、碲，其稀溶液（<1wt%）分別為藍色、橙色和紫色；溶解硫的濃溶液為暗紅色。[4]
| 十四烷基三己基癸酸鏻 | |
|---|---|
phosphonium_decanoate.svg)
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| 別名 | 十四烷基三正己基癸酸鏻 三己基十四烷基癸酸鏻 Cyphos IL 103 |
| 識別 | |
| CAS號 | 465527-65-5 
|
| 性質 | |
| 化學式 | C42H87O2P |
| 摩爾質量 | 655.11 g·mol⁻¹ |
| 密度 | 0.885 g·cm−3[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ K.I. Park, M. Xanthos. A study on the degradation of polylactic acid in the presence of phosphonium ionic liquids. Polymer Degradation and Stability. 2009-05, 94 (5): 834–844 [2021-01-19]. doi:10.1016/j.polymdegradstab.2009.01.030. （原始內容存檔於2018-07-01） （英語）.
- ^ Anna Cieniecka-Rosłonkiewicz, Juliusz Pernak, Joanna Kubis-Feder, Alwar Ramani, Allan J. Robertson, Kenneth R. Seddon. Synthesis, anti-microbial activities and anti-electrostatic properties of phosphonium-based ionic liquids. Green Chemistry. 2005, 7 (12): 855 [2021-01-19]. ISSN 1463-9262. doi:10.1039/b508499g （英語）.
- ^ Qiwei Yang, Dan Xu, Jingzhu Zhang, Yaoming Zhu, Zhiguo Zhang, Chao Qian, Qilong Ren, Huabin Xing. Long-Chain Fatty Acid-Based Phosphonium Ionic Liquids with Strong Hydrogen-Bond Basicity and Good Lipophilicity: Synthesis, Characterization, and Application in Extraction. ACS Sustainable Chemistry & Engineering. 2015-02-02, 3 (2): 309–316 [2021-01-19]. ISSN 2168-0485. doi:10.1021/sc5006796. （原始內容存檔於2022-03-20） （英語）.
- ^ Boros, Èva; Earle, Martyn J.; Gîlea, Manuela A.; Metlen, Andreas; Mudring, Anja-Verena; Rieger, Franziska; Robertson, Allan J.; Seddon, Kenneth R.; Tomaszowska, Alina A.; Trusov, Lev; Vyle, Joseph S. On the dissolution of non-metallic solid elements (sulfur, selenium, tellurium and phosphorus) in ionic liquids. Chem. Commun. 2010, 46 (5): 716–718. ISSN 1359-7345. doi:10.1039/B910469K.