環己基碘
化合物
環己基碘是一種有機化合物，化學式為C6H11I。可由環己醇和氫碘酸加熱反應製得，[4]或由環己烯和碘化氫反應得到[5]，反應中的碘化氫可由碘化鉀和磷酸替代[6]。環己基溴和氫碘酸的鹵素交換也會生成環己基碘。[7]
| 環己基碘 | |
|---|---|
| |
| 英文名 | Iodocyclohexane Cyclohexyl iodide |
| 別名 | 碘代環己烷 NSC 6075 |
| 識別 | |
| CAS號 | 626-62-0 
|
| SMILES |
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| 性質 | |
| 化學式 | C6H11I |
| 摩爾質量 | 210.06 g·mol−1 |
| 密度 | 1.624 g·cm−3（20 °C）[1] |
| 熔點 | 52 °C（325 K）[2] |
| 沸點 | 180—183 °C（453—456 K）[3] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Arthur I. Vogel. Iodides and bromides from alcohols. 1944. GB 565452.
- ^ Robert Truffault. Phosphoric anhydride as a catalyst for the polymerization of unsaturated hydrocarbons. A decahydrobiphenyl obtained by dimerization of cyclohexene. Bulletin de la Societe Chimique de France, Memoires, 1936. 3: 442-459. ISSN: 0366-3132.
- ^ B. Lecea, J.M. Aizpurua, C. Palomo. Reagents and synthetic methods 52. Silane reduction of carbonyl compounds in the presence of iodine. Tetrahedron. 1985-01, 41 (20): 4657–4665 [2019-12-04]. doi:10.1016/S0040-4020(01)82361-9 （英語）.
- ^ Doya, Masaharu; Hoshino, Yuki. Preparation of iodine compounds by alcohol iodination using hydriodic acid while removing generated water. Jpn. Kokai Tokkyo Koho, 2010. JP 2010159223 A
- ^ Breton, Gary W.; Kropp, Paul J.; Harvey, Ronald G. Hydrogen iodide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001.
- ^ IODOCYCLOHEXANE. Organic Syntheses. 1951, 31: 66 [2019-12-04]. doi:10.15227/orgsyn.031.0066. （原始內容存檔於2018-06-02）.
- ^ Mohammad Namavari, N. Satyamurthy, Michael E. Phelps, Jorge R. Barrio. Halogen exchange reactions between alkyl halides and aqueous hydrogen halides. A new method for preparation of alkyl halides.. Tetrahedron Letters. 1990-01, 31 (35): 4973–4976 [2019-12-04]. doi:10.1016/S0040-4039(00)97781-5. （原始內容存檔於2018-07-02） （英語）.