1-溴-3,5-二甲苯
1-溴-3,5-二甲苯是一種有機化合物，化學式為C8H9Br。它可由3,5-二甲基苯胺經重氮化-溴化反應製得。[2]它和苯硼酸在乙酸鈀催化下反應，得到3,5-二甲基聯苯。[3]它和環己基胺在叔丁醇鈉存在下反應，可以得到N-環己基-3,5-二甲基苯胺。[4]
| 1-溴-3,5-二甲苯 | |
|---|---|
| |
| 識別 | |
| CAS號 | 556-96-7 
|
| 性質 | |
| 化學式 | C8H9Br |
| 摩爾質量 | 185.06 g·mol−1 |
| 沸點 | 204 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-3-6].
- ^ Oberboersch, Stefan; Schunk, Stefan; Reich, Melanie; Hees, Sabine; Jostock, Ruth; Engels, Michael; Kless, Achim; Christoph, Thomas; Schiene, Klaus; Germann, Tieno; Bijsterveld, Edward. Preparation of 1-(phenylsulfonyl)piperidines as bradykinin BK1 receptor inhibitors. 2008 WO 2008040492 A1.
- ^ Jairus L. Lamola, Paseka T. Moshapo, Cedric W. Holzapfel, Munaka Christopher Maumela. Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions. RSC Advances. 2021, 11 (43): 26883–26891 [2022-03-06]. ISSN 2046-2069. doi:10.1039/D1RA04947J （英語）.
- ^ Kent O. Kirlikovali, Eunho Cho, Tyler J. Downard, Lilit Grigoryan, Zheng Han, Sooji Hong, Dahee Jung, Jason C. Quintana, Vanessa Reynoso, Sooihk Ro, Yi Shen, Kevin Swartz, Elizabeth Ter Sahakyan, Alex I. Wixtrom, Brandon Yoshida, Arnold L. Rheingold, Alexander M. Spokoyny. Buchwald–Hartwig amination using Pd( i ) dimer precatalysts supported by biaryl phosphine ligands. Dalton Transactions. 2018, 47 (11): 3684–3688 [2022-03-06]. ISSN 1477-9226. doi:10.1039/C8DT00119G （英語）.