碳酸鐳
化合物
碳酸鐳是一種無機化合物,化學式為RaCO3,有強放射性。它可以形成正交晶系晶體,空間群Pmcn。[2]
碳酸鐳 | |||
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英文名 | radium carbonate | ||
識別 | |||
CAS號 | 7116-98-5 | ||
性質 | |||
化學式 | RaCO3 | ||
摩爾質量 | 286.011 g·mol⁻¹ | ||
溶解性(水) | 0.05 g/L(25°C)[1] | ||
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
製備
編輯- Ra2+ + CO32- → RaCO3↓
性質及用途
編輯碳酸鐳可以和酸反應,生成其它鐳化合物:
- RaCO3 + 2 HNO3 → Ra(NO3)2 + 2 H2O
在室溫時,碳酸鐳在碳酸銨或氯化銨濃溶液中的溶解度比碳酸鋇大10倍,藉此可將鐳與鋇分離。[4]它可用於製造鐳鈹中子源。[5]
參考文獻
編輯- ^ Matyskin, Artem V.; Ebin, Burçak; Allard, Stefan; Torapava, Natallia; Eriksson, Lars; Persson, Ingmar; Brown, Paul L.; Ekberg, Christian. Disordered Crystal Structure and Anomalously High Solubility of Radium Carbonate. Inorganic Chemistry. July 21, 2023, 62 (30): 12038–12049. PMC 10394661 . PMID 37477287. doi:10.1021/acs.inorgchem.3c01513.
- ^ Weigel, F.; Trinkl, A. Crystal chemistry of radium. V. Radium salts of inorganic anions. Radiochimica Acta, 1973. 19 (4): 199-202. ISSN: 0033-8230.
- ^ Artem V. Matyskin, Burçak Ebin, Mikhail Tyumentsev, Stefan Allard, Gunnar Skarnemark, Henrik Ramebäck, Christian Ekberg. Disassembly of old radium sources and conversion of radium sulfate into radium carbonate for subsequent dissolution in acid. Journal of Radioanalytical and Nuclear Chemistry. 2016-11, 310 (2): 589–595 [2020-12-10]. ISSN 0236-5731. doi:10.1007/s10967-016-4927-x (英語).
- ^ Nikitin, B. A. Studies on the analytical chemistry of radium. II. Reactions of pure radium. Trav. inst. elat radium (U. S. S. R.), 1937. 3. pp 228-237. CAN31: 32676.
- ^ Bedrich, Fridrich. Preparation of radium-beryllium neutron sources. Sb. Ref. Celostatni Radiochem. Konf., 3, Liblice, Czech., 1964. pp 135. CAN64: 90519.