四十一烷
四十一烷是一种有机化合物，化学式为C41H84。它是聚丙烯（PP）及高密度聚乙烯（HPDE）的催化热解产物之一。[3][4]它可以形成正交晶系的晶体，空间群Pbcm。[5]它的临界点为922 K、0.809 MPa。[6]
| 四十一烷 | |
|---|---|
| |
| 英文名 | Hentetracontane |
| 识别 | |
| CAS号 | 7194-87-8 
|
| 性质 | |
| 化学式 | C41H84 |
| 摩尔质量 | 577.11 g·mol−1 |
| 外观 | 固体 |
| 熔点 | 84.1 °C（357.2 K）（97%纯度样品）[1] 82.3 °C（355.4 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Ahmed Hammami, Anil K. Mehrotra. Non-isothermal crystallization kinetics of n-paraffins: comparison of even-numbered and odd-numbered normal alkanes. Thermochimica Acta. 1993-02, 215: 197–209 [2022-08-17]. doi:10.1016/0040-6031(93)80093-P. （原始内容存档于2018-06-14） （英语）.
- ^ H. Kraack, E. B. Sirota, M. Deutsch. Measurements of homogeneous nucleation in normal-alkanes. The Journal of Chemical Physics. 2000-04-15, 112 (15): 6873–6885 [2022-08-17]. ISSN 0021-9606. doi:10.1063/1.481263. （原始内容存档于2022-03-07） （英语）.
- ^ M. Ismail Khan, Imtiaz Ahmad, Hizbullah Khan, M. Ishaq, Razia Khan, Kashif Gul, Waqas Ahmad. Catalytic Performance of Metal Impregnated Carbon (Darco) in Conversion of Polypropylene and High-Density Polyethylene into Useful Products. Fullerenes, Nanotubes and Carbon Nanostructures. 2015-07-03, 23 (7): 627–639 [2022-08-17]. ISSN 1536-383X. doi:10.1080/1536383X.2014.945167 （英语）.
- ^ Imtiaz Ahmad, Mohammad Ismail Khan, Hizbullah Khan, Mohammad Ishaq, Razia Tariq, Kashif Gul, Waqas Ahmad. Influence of metal-oxide-supported bentonites on the pyrolysis behavior of polypropylene and high-density polyethylene. Journal of Applied Polymer Science. 2015-01-05, 132 (1) [2022-08-17]. doi:10.1002/app.41221. （原始内容存档于2022-08-17） （英语）.
- ^ Steven R. Craig, Gerard P. Hastie, Kevin J. Roberts, John N. Sherwood. Investigation into the structures of some normal alkanes within the homologous series C13H28 to C60H122 using high-resolution synchrotron X-ray powder diffraction. Journal of Materials Chemistry. 1994, 4 (6): 977 [2022-08-17]. ISSN 0959-9428. doi:10.1039/jm9940400977 （英语）.
- ^ Eric W. Lemmon, A. R. H. Goodwin. Critical Properties and Vapor Pressure Equation for Alkanes CnH2n+2: Normal Alkanes With n⩽36 and Isomers for n=4 Through n=9. Journal of Physical and Chemical Reference Data. 2000-01, 29 (1): 1–39 [2022-08-17]. ISSN 0047-2689. doi:10.1063/1.556054. （原始内容存档于2017-12-20） （英语）.
拓展阅读
编辑
- Guangtao Li, Xin Li, Zheng Ouyang, R. Graham Cooks. Carbon-Carbon Bond Activation in Saturated Hydrocarbons by Field-Assisted Nitrogen Fixation. Angewandte Chemie International Edition. 2013-01-14, 52 (3): 1040–1043 [2022-08-17]. doi:10.1002/anie.201207997. （原始内容存档于2022-08-17） （英语）.