氟氯二溴甲烷
化合物
氟氯二溴甲烷是一种有机化合物，化学式为CBr2ClF。它可由氟氯溴乙酸银和溴在180~260 °C反应，或由氟二氯甲烷在650 °C溴化制得。[2]它可用于在有机物中引入氟氯溴甲基。[3][4]
| 氟氯二溴甲烷 | |
|---|---|
| |
| 英文名 | dibromochlorofluoromethane |
| 别名 | FC 11B2 |
| 识别 | |
| CAS号 | 353-55-9 
|
| 性质 | |
| 化学式 | CBr2ClF |
| 摩尔质量 | 226.27 g·mol−1 |
| 沸点 | 80.3 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Reid, Robert J.; Hanson, Edward S.; Pikna, Raymond J. Dibromochlorofluoromethane from dichlorofluoromethane. 1956 US 2755314.
- ^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 227 [2021-10-27]. ISBN 978-0-08-042704-1. （原始内容存档于2021-10-27）.
|issue=被忽略 (帮助) - ^ Clavel, Jean Louis; Langlois, Bernard; Nantermet, Roland; Tordeux, Marc; Wakselman, Claude. Reactions of bromotrifluoromethane and related halides. Part 12. Transformation of disulfides into perfluoroalkyl sulfides in the presence of sulfoxylate anion radical precursors. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992. 24: 3371-3375.
- ^ Jaroslav Kvíčala, Jan Štambaský, Martin Skalický, Oldřich Paleta. Preparation of fluorohalomethylmagnesium halides using highly active magnesium metal and their reactions. Journal of Fluorine Chemistry. 2005-10, 126 (9-10): 1390–1395 [2021-10-27]. doi:10.1016/j.jfluchem.2005.07.016. （原始内容存档于2018-06-13） （英语）.