1,4-二氯丁烷

化合物

1,4-二氯丁烷是一种有机化合物,化学式为C4H8Cl2,它是二氯丁烷同分异构体之一。它可由1,4-丁二醇和氯化试剂(如光气[3]氯化亚砜[4]四氯化碳[5])反应得到。它和咪唑氢化钠的存在下反应,可以得到1,4-二(1-咪唑基)丁烷。[6]

1,4-二氯丁烷
识别
CAS号 110-56-5  checkY
PubChem 8059
SMILES
 
  • ClCCCCCl
性质
化学式 C4H8Cl2
摩尔质量 127.01 g·mol−1
外观 无色液体
密度 1.1324 g·cm−3(25 °C)[1]
熔点 −37.3 °C(235.8 K)[2]
沸点 161 °C(434 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1,4-二氯丁烷是生产尼龙的前体。[7][8]

参考文献

编辑
  1. ^ Herbert C. Brown, Arthur B. Asii. Isomer Distribution in the Sulfuryl Chloride Chlorination of the 1-Chlorobutanes and Related Compounds; the Inductive Effect in Free Radical Substitutions 1. Journal of the American Chemical Society. 1955-08, 77 (15): 4019–4024 [2020-11-30]. ISSN 0002-7863. doi:10.1021/ja01620a019 (英语). 
  2. ^ 2.0 2.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-11-30].
  3. ^ Ettl, Roland; Reuther, Wolfgang. Preparation of alkyl chlorides from the corresponding alcohols. 1995. EP 645357 A1.
  4. ^ F. D. Gunstone, P. J. Sykes. 590. Fatty acids. Part VII. The synthesis of hexadeca-8,10-dienoic, octadeca-7,11-dienoic, and eicosa-7,13-dienoic acid. Journal of the Chemical Society (Resumed). 1962: 3055 [2020-11-30]. ISSN 0368-1769. doi:10.1039/jr9620003055 (英语). 
  5. ^ Ravil I. Khusnutdinov, Alfiya R. Bayguzina, Rigina S. Asylbaeva, Rishat I. Aminov, Usein M. Dzhemilev. Synthesis of N-aryl-substituted pyrrolidines and piperidines by reaction of anilines with α,ω-diols catalyzed by FeCl3.6H2O in carbon tetrachloride. Arkivoc. 2014-09-13, 2014 (5): 341–350 [2020-11-30]. ISSN 1551-7012. doi:10.3998/ark.5550190.p008.743. (原始内容存档于2020-11-26) (英语). 
  6. ^ Nader Ghaffari Khaligh, Taraneh Mihankhah, Mohd Rafie Johan, Juan Joon Ching. Two novel binuclear sulfonic-functionalized ionic liquids: Influence of anion and carbon-spacer on catalytic efficiency for one-pot synthesis of bis(indolyl)methanes. Journal of Molecular Liquids. 2018-06, 259: 260–273 [2020-11-30]. doi:10.1016/j.molliq.2018.03.044 (英语). 
  7. ^ Mark S. M. Alger. Polymer Science Dictionary. Springer. 1997: 241 [August 28, 2008]. ISBN 0-412-60870-7. Google Book Search. (原始内容存档于2022-12-27). 
  8. ^ Rossberg, Manfred; Lendle, Wilhelm; Pfleiderer, Gerhard; Tögel, Adolf; Dreher, Eberhard-Ludwig; Langer, Ernst; Rassaerts, Heinz; Kleinschmidt, Peter; Strack, Chlorinated Hydrocarbons, Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2005, doi:10.1002/14356007.a06_233.pub2