4,4'-[(3,3,4,4,5,5-六氟环戊-1-烯-1,2-二基)双(5-甲基噻吩-4,2-二基)]二吡啶
4,4'-[(3,3,4,4,5,5-六氟环戊-1-烯-1,2-二基)双(5-甲基噻吩-4,2-二基)]二吡啶是一种有机化合物，它可以八氟环戊烯和3-溴-2-甲基-5-(4-吡啶基)噻吩为原料反应得到。[3]它可以和金属形成配位化合物[3]或金属有机框架材料[4]。
| 4,4'-[(3,3,4,4,5,5-六氟环戊-1-烯-1,2-二基)双(5-甲基噻吩-4,2-二基)]二吡啶 | |
|---|---|
bis(5-methylthiophenediyl)bispyridine.png)
| |
| 英文名 | 4,4'-[(3,3,4,4,5,5-Hexafluoro-1-cyclopentene-1,2-diyl)bis(5-methyl-4,2-thiophenediyl)]bis[pyridine] |
| 别名 | 4,4'-[(3,3,4,4,5,5-六氟环戊-1-烯-1,2-二基)双(5-甲基-4,2-噻吩二基)]二吡啶 1,2-双[2'-甲基-5'-(吡啶-4''-基)噻吩-3'-基]六氟环戊烯 PDTEo PyDTEopen |
| 识别 | |
| CAS号 | 154566-71-9 
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| SMILES |
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| 性质 | |
| 化学式 | C25H16F6N2S2 |
| 摩尔质量 | 522.53 g·mol⁻¹ |
| 外观 | 白色粉末[1] |
| 密度 | 1.48±0.1 g·cm−3（20 °C）[2] |
| 溶解性（水） | 4.8×10−5 g（25 °C）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
bispyridine.png)
参考文献
编辑- ^ 1.0 1.1 Sylvain L. Gilat, Stephen H. Kawai, Jean-Marie Lehn. Light-Triggered Molecular Devices: Photochemical Switching Of optical and Electrochemical Properties in Molecular Wire Type Diarylethene Species. Chemistry - A European Journal. 1995-08, 1 (5): 275–284 [2020-08-20]. doi:10.1002/chem.19950010504 （英语）.
- ^ 2.0 2.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-08-20]
- ^ 3.0 3.1 Andreu Presa, Guillem Vázquez, Leoní A. Barrios, Olivier Roubeau, Luís Korrodi-Gregório, Ricardo Pérez-Tomás, Patrick Gamez. Photoactivation of the Cytotoxic Properties of Platinum(II) Complexes through Ligand Photoswitching. Inorganic Chemistry. 2018-04-02, 57 (7): 4009–4022 [2020-08-20]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.8b00146. （原始内容存档于2021-09-23） （英语）.
- ^ Hiroshi Sato, Toshiya Matsui, Zhiyi Chen, Jenny Pirillo, Yuh Hijikata, Takuzo Aida. Photochemically Crushable and Regenerative Metal–Organic Framework. Journal of the American Chemical Society. 2020-08-19, 142 (33): 14069–14073 [2020-08-20]. ISSN 0002-7863. doi:10.1021/jacs.0c06615 （英语）.
- ^ Sumin Lee, Youngmin You, Kei Ohkubo, Shunichi Fukuzumi, Wonwoo Nam. Mechanism and Fluorescence Application of Electrochromism in Photochromic Dithienylcyclopentene. Organic Letters. 2012-05-04, 14 (9): 2238–2241 [2020-08-20]. ISSN 1523-7060. doi:10.1021/ol300604n （英语）.