8-氯荧蒽
8-氯荧蒽是一种氯代芳烃，化学式为C16H9Cl。它可由4-氯苯硼酸和1,8-二溴萘在钯配合物催化下反应制得；[1]或由8-氨基荧蒽和亚硝酸钠在酸性条件下反应，再氯化得到。[2]它和双频哪醇二硼在催化下反应，可以得到荧蒽-8-硼酸频哪醇酯。[3]
| 8-氯荧蒽 | |
|---|---|
| 识别 | |
| CAS号 | 145730-31-0 
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| SMILES |
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| 性质 | |
| 化学式 | C16H9Cl |
| 摩尔质量 | 236.7 g·mol−1 |
| 外观 | 黄色固体[1] |
| 熔点 | 108-110 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 1.2 Nahed Ketata, Linhao Liu, Ridha Ben Salem and Henri Doucet. Mono or double Pd-catalyzed C–H bond functionalization for the annulative π-extension of 1,8-dibromonaphthalene: a one pot access to fluoranthene derivatives. Beilstein J. Org. Chem. 2024, 20, 427–435. doi:10.3762/bjoc.20.37.
- ^ Van Haeringen, C. J.; Lugtenburg, J.; Cornelisse, J. (1996). Synthesis and Characterization of Chloro-, Bromo-, Cyano-, Formyl-, and Methylfluoranthenes. Polycyclic Aromatic Compounds, 8 (1), 9–22. doi:10.1080/10406639608048330.
- ^ Kim, Minjun; Lee, Dong Hoon; Suh, Sang Duk; Kim, Young Seok; Kim, Donghee; Oh, Joongsuk; Lee, Da Jung. Preparation of triazine-linked dibenzofuran compounds and organic light-emitting devices comprising them. 2023. WO2023003146 A1.