一碲化镱
化合物
一碲化镱是一种无机化合物，为镱的碲化物之一，化学式YbTe。它可由碲化镱（Yb2Te3）的高温还原反应制得，[1]或氯化镱、碲和氢气反应得到：[2]
| 一碲化镱 | |
|---|---|
| |
| 识别 | |
| CAS号 | 12125-58-5 
|
| 性质 | |
| 化学式 | TeYb |
| 摩尔质量 | 300.64 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
- YbCl3 + H2 → YbCl2 + 2 HCl
- YbCl2 + H2 + Te → YbTe + 2 HCl
[(py)2Yb(μ-η2-η2-PhNNPh)(TePh)]2·2py的热分解也会生成一碲化镱，但同时会产生氮化镱。[3]
参考文献
编辑- ^ Senff, Heinz; Klemm, Wilhelm. Measurements on bivalent and quadrivalent compounds of the rare earths. IX. The selenides and tellurides of bivalent ytterbium. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1939. 242: 92-96.
- ^ Obolonchik, V. A.; Yanaki, A. A. Synthesis of some rare-earth metal tellurides. Khal'kogenidy, 1970. 2: 141-148. CODEN D8MMYC.
- ^ Anna Kornienko, Deborah Freedman, Thomas J. Emge, John G. Brennan. Heteroleptic Lanthanide Compounds with Chalcogenolate Ligands: Reduction of PhNNPh/PhEEPh (E = Se or Te) Mixtures with Ln (Ln = Ho, Er, Tm, Yb). Thermolysis Can Give LnN or LnE. Inorganic Chemistry. 2001-01-01, 40 (1): 140–145 [2023-06-13]. ISSN 0020-1669. doi:10.1021/ic000499y. （原始内容存档于2023-05-10） （英语）.
拓展阅读
编辑
- Ziya S. Aliev, Gulnara I. Ibadova, Jean-Claude Tedenac, Mahammad B. Babanly. Study of the YbTe–SnTe–Sb2Te3 quasi-ternary system. Journal of Alloys and Compounds. 2014-07, 602: 248–254 [2023-06-13]. doi:10.1016/j.jallcom.2014.03.036. （原始内容存档于2018-06-09） （英语）.
- Martin Siron, Oxana Andriuc, Kristin A. Persson. Data-Driven Investigation of Tellurium-Containing Semiconductors for CO 2 Reduction: Trends in Adsorption and Scaling Relations. The Journal of Physical Chemistry C. 2022-08-11, 126 (31): 13224–13236 [2023-06-13]. ISSN 1932-7447. doi:10.1021/acs.jpcc.2c04810. （原始内容存档于2023-05-16） （英语）.