钨酸锰

化合物

钨酸锰是一种无机化合物,化学式为MnWO4。它在自然界中以Hübnerite英语Hübnerite矿物的形式存在。[4]

钨酸锰
别名 钨酸亚锰
钨酸锰(II)
识别
CAS号 14177-46-9(无水)  checkY
866597-81-1(水合)  checkY
性质
化学式 MnO4W
摩尔质量 302.78 g·mol−1
外观 白色[1]或棕色固体[2][3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备及反应

编辑

钨酸锰可由氯化锰钨酸钠在水溶液中反应制得[5],或由三氧化二锰三氧化钨高温反应制得:[6]

MnCl2 + Na2WO4 → MnWO4 + 2 NaCl
Mn2O3 + 2 WO3 → 2 MnWO4 + 12O2

它和在800 °C反应,可以得到MnWN2[7]它和Pr2WO6在高温反应,可以得到棕色的MnPr2W2O10[8]

参考文献

编辑
  1. ^ Do Dang Trung; et al. Controlled synthesis of manganese tungstate nanorods for highly selective NH3 gas sensor. Journal of Alloys and Compounds, 2018. 735. doi:10.1016/j.jallcom.2017.11.161.
  2. ^ Saeid Khademolhoseini & Ali Abedini. Investigation of the structural, optical and magnetic properties of manganese tungstate nanoparticles synthesized via a sonochemical method. Journal of Materials Science: Materials in Electronics, 2016. 27. doi:10.1007/s10854-016-4790-0
  3. ^ Somchai Thongtem, Surangkana Wannapop, Anukorn Phuruangrat, Titipun Thongtem. Cyclic microwave-assisted spray synthesis of nanostructured MnWO4. Materials Letters. 2009. 63 (11): 833-836.
  4. ^ Hübnerite. mindat.org. [2024-07-27]
  5. ^ Shu-Jian Chen, Xue-Tai Chen, Ziling Xue, Jian-Hao Zhou, ing Li, Jian-Ming Hong and Xiao-Zeng You. Morphology control of MnWO4 nanocrystals by a solvothermal route. J. Mater. Chem., 2003,13, 1132-1135. doi:10.1039/B300457K.
  6. ^ Bak, T.; Ziolkowski, J. Kinetics and mechanism of synthesis of cobalt and manganese tungstates. Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques. 1974, 22 (4): 333–340. ISSN 0001-4095. 
  7. ^ Jekabs Grins, Per-Olov Käll and Gunnar Svensson. Synthesis and structural characterisation of MnWN2 prepared by ammonolysis of MnWO4. J. Mater. Chem., 1995,5, 571-575. doi:10.1039/JM9950500571.
  8. ^ E. Tomaszewicz. New praseodymium(III) and d-electron metals tungstates of the formula MPr2W2O10 (M=Mn, Co, Cd). Journal of Thermal Analysis and Calorimetry, 2008. 93. 711-715. doi:10.1007/s10973-008-9133-9.