1,7-二溴庚烷
化合物
1,7-二溴庚烷是一种有机化合物，化学式为C7H14Br2。它可由1,7-庚二醇和三溴化磷在乙醚重反应得到，[4]或和氢溴酸在相转移催化剂的存在下反应制得。[5]它具有卤代烃（溴代烃）的通性，如在碳酸钾的存在下和4-巯基苯酚反应，得到1,7-二(4-羟基苯硫基)庚烷。[6]它在丙酮中和碘化钠反应，可以得到1,7-二碘庚烷。[7]
| 1,7-二溴庚烷 | |
|---|---|
| |
| 识别 | |
| CAS号 | 4549-31-9 
|
| 性质 | |
| 化学式 | C7H14Br2 |
| 摩尔质量 | 257.99 g·mol⁻¹ |
| 密度 | 1.5306 g·cm−3（20 °C）[1] |
| 熔点 | −41.7 °C（231.5 K）[2] |
| 沸点 | 263 °C（536 K）[3] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Muller, Adolf; Vanc, Wenzel. Multimembered cyclic compounds. XII. Formation of ω,ω'-oxidoalkanes and ω,ω'-dibromodialkyl ethers from diprimary glycols and hydrogen bromide. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1944, 77B. 669-675. ISSN: 0365-9488.
- ^ William P. Hall, E. Emmet Reid. A Series of α,ι-Dimercaptans 1. Journal of the American Chemical Society. 1943-08, 65 (8): 1466–1468 [2020-11-28]. ISSN 0002-7863. doi:10.1021/ja01248a008. （原始内容存档于2020-12-10） （英语）.
- ^ Gordon G. Cash, Suzanne Hartigan, Jay Tunkel. Normal boiling points of haloalkanes from electrotopological state indices. Toxicological & Environmental Chemistry. 2008-11, 90 (6): 1073–1089 [2020-11-28]. ISSN 0277-2248. doi:10.1080/02772240701862116 （英语）.
- ^ Ben-Sasson, Shmuel; Gross, Einav. Compounds and uses for the treatment and prevention of diseases and conditions associate with or aggravated by impaired mitophagy. 2019. WO 2019175873 A1.
- ^ Guoqin Hu, Hua Li, Juan Liu, Jiang Zhu. Preparation of Supported CTAB/MCM-41 and CTAB-Nafion/MCM-41 Mesoporous Molecular Sieve and Their Use in the Brominating Reaction. Journal of the Korean Chemical Society. 2011-08-20, 55 (4): 691–696 [2020-11-28]. ISSN 1017-2548. doi:10.5012/jkcs.2011.55.4.691. （原始内容存档于2018-06-04） （英语）.
- ^ Yuki Arakawa, Kenta Komatsu, Satoyoshi Inui, Hideto Tsuji. Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase. Journal of Molecular Structure. 2020-01, 1199: 126913 [2020-11-28]. doi:10.1016/j.molstruc.2019.126913 （英语）.
- ^ Manuel Petroselli, Venkatachalam Angamuthu, Faiz-Ur Rahman, Xinluo Zhao, Yang Yu, Julius Rebek. Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems. Journal of the American Chemical Society. 2020-02-05, 142 (5): 2396–2403 [2020-11-28]. ISSN 0002-7863. doi:10.1021/jacs.9b11595. （原始内容存档于2022-04-19） （英语）.