2,7-二氮杂芘是一种有机化合物,化学式为C14H8N2。它可以1,4,5,8-萘四甲酸二酐甲胺水溶液反应,再与氯化铝-氢化铝锂反应后,在钯碳存在下脱除甲基得到。[1]它和碘甲烷反应,可以得到2-甲基-2,7-二氮杂芘碘化物或2,7-二甲基-2,7-二氮杂芘二碘化物。[2][3]

2,7-二氮杂芘
别名 苯并[lmn][3,8]菲咯啉
识别
CAS号 194-00-3  checkY
SMILES
 
  • N=1C=C2C=CC3=CN=CC=4C=CC(C1)=C2C34
性质
化学式 C14H8N2
摩尔质量 204.23 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Sehnal, Petr; Holý, Petr; Tichý, Miloš; Závada, Jiří; Císařová, Ivana (2002). 4,4'-Bipyridine-2,2',6,6'-tetracarboxamide. Synthesis and Self-Assembling Properties of the Free Base and the 1 : 1 Silver(I) Triflate Complex. Collection of Czechoslovak Chemical Communications, 67 (8), 1236–1246. doi:10.1135/cccc20021236.
  2. ^ A. John Blacker, Jaroslaw Jazwinski, Jean-Marie Lehn. Molecular Anion Binding and Substrate Photooxidation in Visible Light by 2,7-Diazapyrenium Cations. Helvetica, 1987. 70 (1): 1-12. doi:10.1002/hlca.19870700102.
  3. ^ Laura M. Grimm, Stephan Sinn, Marjan Krstić, Elisa D'Este, Ivo Sonntag, Eko Adi Prasetyanto, Thomas Kuner, Wolfgang Wenzel, Luisa De Cola, Frank Biedermann. Fluorescent Nanozeolite Receptors for the Highly Selective and Sensitive Detection of Neurotransmitters in Water and Biofluids. Adv. Mater. 2021. 33 (49). 2104614. doi:10.1002/adma.202104614.