2-硝基溴苯

2-硝基溴苯
识别
CAS号	577-19-5
SMILES	Brc1ccccc1[N+](=O)[O-];
性质
化学式	C6H4BrNO2
摩尔质量	202.01 g·mol⁻¹
熔点	41—42 °C（314—315 K）
沸点	258—265 °C（531—538 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2-硝基溴苯是一种有机化合物，化学式为C₆H₄BrNO₂。它可以在溴苯的硝化反应中生成，但并非主产物。^[3]^[4]2-硝基苯胺的重氮化-溴化反应^[5]以及2-溴苯胺的氧化反应^[6]可以以较高产率得到2-硝基溴苯。

参考文献

^ Robert A. Benkeser, Philip E. Brumfield. Nitration of Organosilicon Compounds with Copper Nitrate. Journal of the American Chemical Society. 1951-10, 73 (10): 4770–4773 [2021-05-19]. ISSN 0002-7863. doi:10.1021/ja01154a087 （英语）.
^ Inagaki, Sigenobu. Diphenylisatin and its derivatives. IV. Monobromo derivatives of dianisoleisatin and its oxidation product. Yakugaku Zasshi, 1938. 58: 961-975. ISSN: 0031-6903.
^ Radoslaw R Bak, Andrew J Smallridge. A fast and mild method for the nitration of aromatic rings. Tetrahedron Letters. 2001-09, 42 (38): 6767–6769 [2021-05-19]. doi:10.1016/S0040-4039(01)01378-8. （原始内容存档于2020-11-06）（英语）.
^ Christopher G Frost, Joseph P Hartley, David Griffin. Counterion effects in indium-catalysed aromatic electrophilic substitution reactions. Tetrahedron Letters. 2002-07, 43 (27): 4789–4791 [2021-05-19]. doi:10.1016/S0040-4039(02)00931-0. （原始内容存档于2018-07-01）（英语）.
^ Woonphil Baik, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, Byeong Hyo Kim. Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ. Canadian Journal of Chemistry. 2005-03-01, 83 (3): 213–219 [2021-05-19]. ISSN 0008-4042. doi:10.1139/v05-026 （英语）.
^ Jia Liu, Jue Li, Jiangmeng Ren, Bu-Bing Zeng. Oxidation of aromatic amines into nitroarenes with m-CPBA. Tetrahedron Letters. 2014-02, 55 (9): 1581–1584 [2021-05-19]. doi:10.1016/j.tetlet.2014.01.073. （原始内容存档于2018-06-10）（英语）.

[1] Robert A. Benkeser, Philip E. Brumfield. Nitration of Organosilicon Compounds with Copper Nitrate. Journal of the American Chemical Society. 1951-10, 73 (10): 4770–4773 [2021-05-19]. ISSN 0002-7863. doi:10.1021/ja01154a087 （英语）.

[2] Inagaki, Sigenobu. Diphenylisatin and its derivatives. IV. Monobromo derivatives of dianisoleisatin and its oxidation product. Yakugaku Zasshi, 1938. 58: 961-975. ISSN: 0031-6903.

[3] Radoslaw R Bak, Andrew J Smallridge. A fast and mild method for the nitration of aromatic rings. Tetrahedron Letters. 2001-09, 42 (38): 6767–6769 [2021-05-19]. doi:10.1016/S0040-4039(01)01378-8. （原始内容存档于2020-11-06）（英语）.

[4] Christopher G Frost, Joseph P Hartley, David Griffin. Counterion effects in indium-catalysed aromatic electrophilic substitution reactions. Tetrahedron Letters. 2002-07, 43 (27): 4789–4791 [2021-05-19]. doi:10.1016/S0040-4039(02)00931-0. （原始内容存档于2018-07-01）（英语）.

[5] Woonphil Baik, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, Byeong Hyo Kim. Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ. Canadian Journal of Chemistry. 2005-03-01, 83 (3): 213–219 [2021-05-19]. ISSN 0008-4042. doi:10.1139/v05-026 （英语）.

[6] Jia Liu, Jue Li, Jiangmeng Ren, Bu-Bing Zeng. Oxidation of aromatic amines into nitroarenes with m-CPBA. Tetrahedron Letters. 2014-02, 55 (9): 1581–1584 [2021-05-19]. doi:10.1016/j.tetlet.2014.01.073. （原始内容存档于2018-06-10）（英语）.

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2-硝基溴苯

识别
CAS号	577-19-5 ^Y
SMILES	Brc1ccccc1[N+](=O)[O-]
性质
化学式	C₆H₄BrNO₂
摩尔质量	202.01 g·mol⁻¹
熔点	41—42 °C（314—315 K）^[1]
沸点	258—265 °C（531—538 K）^[2]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。