二烴基硼酸
二烴基硼酸是硼酸的兩個羥基被烴基取代得到的有機硼化合物,其通式為R2BOH。它的羥基氫被烴基取代,可以得到二烴基硼酸酯(R2BOR')。
![](http://upload.wikimedia.org/wikipedia/commons/thumb/b/b1/Borinic-acid-2D.png/220px-Borinic-acid-2D.png)
二烴基硼酸及其衍生物
編輯常見的物質見列表:
R2BOR' | 酸 R'=H | 酸酐 | 酯R' | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
R | 氫(H) | 氧(-O-) | 氨基乙基 | 乙基 | 正丙基 | 正丁基 | 3-甲基丙基 | 1-甲基丙基 | 苯基 | 乙二氧二基 | 甲基 | 8-喹啉基 |
苯基 | [1] | cas 524-95-8 | cas 43185-52-0 | cas 15323-04-3 | cas 13471-36-8 | SID 535455 | ||||||
o-甲苯基 | ||||||||||||
m-甲苯基 | ||||||||||||
p-甲苯基 | [2] | |||||||||||
p-茴香基 | [3] | |||||||||||
p-聯苯基 | [4] | |||||||||||
p-氯苯基 | cas 89566-59-6 | [5] | cas 61733-90-2 | cas 564483-61-0 | ||||||||
3-氯苯基 | cas 433338-06-8 | |||||||||||
α-萘基 | [6] | [7] cas 6962-88-5 | ||||||||||
β-萘基 | [3] | |||||||||||
p-溴苯基 | [3] | [8] | ||||||||||
2-甲基-5-氯苯基 | [5] | |||||||||||
2-噻吩基 | [9] SID 3881207 | SID 8142470 | ||||||||||
mesityl | sid 4278417 CAS 20631-84-9[10][11][12] | |||||||||||
甲基 | cas 13061-97-7 | cas 86610-16-4 | cas 4443-43-0 | |||||||||
乙基 | cas 4426-31-7 | [13] 7318-84-5 | cas 7397-46-8 | |||||||||
烯丙基 | ||||||||||||
正丁基 | cas 1189-31-7 | [14] | cas 19324-14-2 | cas 2344-21-0 | cas 2344-21-0 | |||||||
4-甲基丁基 | ||||||||||||
2-氯乙烯基 | [15] | |||||||||||
3,5-二甲基苯基 | [16] | |||||||||||
丙基 | cas 53678-60-7 | cas 2938-89-8 | ||||||||||
1-甲基丙基 | cas 4026-69-1 | |||||||||||
2-甲基丙基 | cas 4026-82-8 |
參考文獻
編輯- ^ Lange, Thomas; Böhme, Uwe; Roewer, Gerhard. Crystal structure of tetraphenyldiboroxane a monomer diboroxane. Inorganic Chemistry Communications. 2002, 5 (6): 377–379. doi:10.1016/S1387-7003(02)00402-1.
- ^ Erbes, Michael; Klaus Forstinger; Andreas Meudt. Process for preparing boronic and borinic acids. US Patent 20020161230. 31 Oct 2002 [15 October 2013]. (原始內容存檔於2016-03-06).
- ^ 3.0 3.1 3.2 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 24
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 25
- ^ 5.0 5.1 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 26
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 5
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 9
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 2
- ^ Low, John Nicolson; Musgrave, Oliver; Wardell, James. (2-Aminoethoxy)bis(2-thienyl)boron. Acta Crystallographica Section C. 15 February 2000, 56 (2): e63. doi:10.1107/S0108270100000482.
- ^ Birch, Samuel J.; Boss, Sally R.; Cole, Sarah C.; Coles, Martyn P.; Haigh, Robert; Hitchcock, Peter B.; Wheatley, Andrew E. H. The structural characteristics of organozinc complexes incorporating N,N?-bidentate ligands. Dalton Transactions. 1 January 2004, (21): 3568–3574. PMID 15510278. doi:10.1039/B410945G.
- ^ Kuhlmann, Matthias; Baumgartner, Thomas; Parvez, Masood. A new polymorph of dimesitylborinic acid. Acta Crystallographica Section E. 7 June 2008, 64 (7): o1185. PMC 2961869 . PMID 21202827. doi:10.1107/S1600536808015638.
- ^ Weese, Kenneth J.; Bartlett, Ruth A.; Murray, Brendan D.; Olmstead, Marilyn M.; Power, Philip R. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2). Inorganic Chemistry. 1 July 1987, 26 (15): 2409–2413. doi:10.1021/ic00262a015.
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 28
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 17
- ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. (原始內容 (PDF)存檔於2016-03-05). ref 29
- ^ Winkle, D. boronic acids can be used as viable alternatives to borinic acids in suzuki coupling reactions. Organic Process Research & Development. 2001, 5 (4): 450–451. doi:10.1021/op010207s.[失效連結]