鎢酸鋅

化合物

鎢酸鋅是一種無機化合物,化學式為ZnWO4,它在自然界以和鐵共生的鎢鋅礦德語Sanmartinit的形式存在。它可由氯化鋅硝酸鋅鎢酸鈉在水溶液中反應得到。[2][3][4]

鎢酸鋅

識別
CAS號 13597-56-3  checkY
性質
化學式 ZnWO
4
莫耳質量 313.22 g·mol⁻¹
外觀 白色固體[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

它和稀土單鎢酸鹽(RE2O2WO4)在高溫加熱反應,可以結晶出ZnRE4W3O16(RE=Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, Lu)。[5]

參考文獻

編輯
  1. ^ Tiziano Montini; et al. Synthesis, characterization and photocatalytic performance of transition metal tungstates. Chemical Physics Letters, 2010. 498 (1-3): 113-119. doi:10.1016/j.cplett.2010.08.026.
  2. ^ Eric da Cruz Severo, Ederson Rossi Abaide, Chayene Gonçalves Anchieta, Vitória Segabinazzi Foletto, Caroline Trevisan Weber, Tais Bisognin Garlet, Gabriela Carvalho Collazzo, Marcio Antonio Mazutti, André Gündel, Raquel Cristine Kuhn, Edson Luiz Foletto: Preparation of Zinc Tungstate (ZnWO4) Particles by Solvo-hydrothermal Technique and their Application as Support for Inulinase Immobilization. In: Materials Research. 2016, S. 0, doi:10.1590/1980-5373-MR-2015-0100.
  3. ^ Mehdi Rahimi-Nasrabadi, Seied Mahdi Pourmortazavi, Mohammad Reza Ganjali, Seiedeh Somayyeh Hajimirsadeghi, Mir Mahdi Zahedi: Electrosynthesis and characterization of zinc tungstate nanoparticles. In: Journal of Molecular Structure. 1047, 2013, S. 31, doi:10.1016/j.molstruc.2013.04.050.
  4. ^ Saman Rahnamaeiyan, Mahdi Nasiri, Amin Alborzi, S. Mahdi Tabatabaei: Sonochemical synthesis and characterization of zinc tungstate nanoparticles and investigation of its photocatalyst application. In: Journal of Materials Science: Materials in Electronics. 27, 2016, S. 1113, doi:10.1007/s10854-015-3859-5.
  5. ^ E. Tomaszewicz. Synthesis and some properties of new zinc and rare-earth metal tungstates ZnRE4W3O16. Solid State Sciences. 2006-05, 8 (5): 508–512 [2023-02-13]. doi:10.1016/j.solidstatesciences.2005.12.009. (原始內容存檔於2018-06-28) (英語).