2-溴苯胺
化合物
2-溴苯胺是一種有機化合物，化學式為BrC6H4NH2。它可由2-硝基溴苯經水合肼[4]或氫氣[5]還原製得。它和N-溴代丁二醯亞胺反應，得到2,4-二溴苯胺。[6]它和乙酸酐反應，得到2-乙醯氨基溴苯。[7]
| 2-溴苯胺 | |
|---|---|
| |
| 識別 | |
| CAS號 | 615-36-1 
|
| 性質 | |
| 化學式 | C6H6BrN |
| 摩爾質量 | 172.02 g·mol−1 |
| 密度 | 1.52 g·cm−3[1] |
| 熔點 | 31—32 °C（304—305 K）[2] |
| 沸點 | 126 °C（399 K）（29 torr）[3] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Manuel A. V. Ribeiro da Silva, Ana I. M. C. L. Ferreira, José R. B. Gomes. Experimental and Computational Study on the Thermochemistry of Bromoanilines. Bulletin of the Chemical Society of Japan. 2006-12, 79 (12): 1852–1859 [2021-06-26]. ISSN 0009-2673. doi:10.1246/bcsj.79.1852. （原始內容存檔於2019-08-21） （英語）.
- ^ Raymond G. Wallace, John M. Barker, Michael L. Wood. Migration to Electron-Deficient Nitrogen. A One Pot Synthesis of Aromatic and Heteroaromatic Amines from Carboxylic Acids. Synthesis. 1990, 1990 (12): 1143–1144 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-1990-27117. （原始內容存檔於2018-06-02） （英語）.
- ^ Wataru Ando, Hidetoshi Tsumaki. Synthetic Application of Aminosilanes: Selective Bromination of Anilines via Reaction of Anilinosilanes with N -Bromosuccinimide. Synthesis. 1982, 1982 (04): 263–264 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-1982-29770. （原始內容存檔於2018-06-03） （英語）.
- ^ Jing Lv, Zhengtang Liu, Zhengping Dong. Iron oxide modified N-doped porous carbon derived from porous organic polymers as a highly-efficient catalyst for reduction of nitroarenes. Molecular Catalysis. 2020-12, 498: 111249 [2021-06-26]. doi:10.1016/j.mcat.2020.111249 （英語）.
- ^ Dong-Fang Hou, Zhi-Feng Jiao, Zai-Peng Liang, Yun-Wei Wang, Xiao-Ning Guo, Xiang-Yun Guo. Selectivity control of Pt/SiC catalysts for photothermocatalytic hydrogenation of 3-nitrostyrene. Applied Surface Science. 2020-10, 526: 146616 [2021-06-26]. doi:10.1016/j.apsusc.2020.146616 （英語）.
- ^ Rama Moorthy Appa, Bandameeda Ramesh Naidu, Jangam Lakshmidevi, Jyothi Vantikommu, Katta Venkateswarlu. Added catalyst-free, versatile and environment beneficial bromination of (hetero)aromatics using NBS in WEPA. SN Applied Sciences. 2019-10, 1 (10) [2021-06-26]. ISSN 2523-3963. doi:10.1007/s42452-019-1274-x （英語）.
- ^ Jaeyoung Ban, Minkyung Lim, Saira Shabbir, Junghyun Baek, Hakjune Rhee. Site-Specific Synthesis of Carbazole Derivatives through Aryl Homocoupling and Amination. Synthesis. 2020-03, 52 (06): 917–927 [2021-06-26]. ISSN 0039-7881. doi:10.1055/s-0039-1690759 （英語）.