三(2-吡啶基)膦
化合物
三(2-吡啶基)膦是一种有机化合物，化学式为C15H12N3P，它是三吡啶基膦的同分异构体之一。它可由2-溴吡啶和红磷在碱性条件下反应制得。[2]它和灰硒回流，可以得到三(2-吡啶基)硒化膦。[3]
| 三(2-吡啶基)膦 | |
|---|---|
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| 识别 | |
| CAS号 | 26437-48-9 
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| PubChem | 11065346 |
| SMILES |
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| 性质 | |
| 化学式 | C15H12N3P |
| 摩尔质量 | 265.25 g·mol−1 |
| 熔点 | 113—114 °C（386—387 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ W. Cule Davies, Frederick G. Mann. 74. The stereochemistry of organic derivatives of phosphorus. Part I. The synthesis of acidic and basic dissymmetric tertiary phosphines. The optical resolution of phenyl-p-(carboxymethoxy)phenyl-n-butylphosphine sulphide. Journal of the Chemical Society (Resumed). 1944: 276 [2020-09-20]. ISSN 0368-1769. doi:10.1039/jr9440000276 （英语）.
- ^ Svetlana N. Arbuzova, Nina K. Gusarova, Tatyana E. Glotova, Igor A. Ushakov, Svetlana I. Verkhoturova, Anastasiya O. Korocheva, Boris A. Trofimov. Reaction of Tri(2-pyridyl)phosphine with Electron-Deficient Alkynes in Water: Stereoselective Synthesis of Functionalized Pyridylvinylphosphine Oxides: Stereoselective Synthesis of Pyridylvinylphosphine Oxides. European Journal of Organic Chemistry. 2014-01, 2014 (3): 639–643 [2020-09-20]. doi:10.1002/ejoc.201301453 （英语）.
- ^ Xuecheng Hu, Tingquan Sun, Chunyang Zheng. Synthesis, crystal structures and magnetic properties of two iron (II) tris(pyridyl)phosphine selenides complexes. Phosphorus, Sulfur, and Silicon and the Related Elements. 2018-05-04, 193 (5): 300–305 [2020-09-20]. ISSN 1042-6507. doi:10.1080/10426507.2017.1417295 （英语）.