环己烷甲酸缩水甘油酯

环己烷甲酸缩水甘油酯是一种有机化合物,化学式为C10H16O3,它是一种无色油状液体。[1][2]

环己烷甲酸缩水甘油酯
识别
CAS号 24553-05-7  checkY
SMILES
 
  • O=C(OCC1OC1)C2CCCCC2
性质
化学式 C10H16O3
摩尔质量 184.23 g·mol−1
外观 无色油状液体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备及反应

编辑

环己烷甲酸缩水甘油酯可由环己烷甲酰氯缩水甘油4-二甲氨基吡啶存在下反应制得,[1]或由环己烷甲酸碳酸钾环氧溴丙烷維基數據所列Q27109087二甲基甲酰胺中反应得到。[2]

它和吡咯烷异丙醇中加热反应,可以得到环己烷甲酸-2-羟基-3-吡咯烷基丙酯。[2]

参考文献

编辑
  1. ^ 1.0 1.1 George Acquaah-Harrison, Shu Zhou, Jennifer V. Hines, and Stephen C. Bergmeier. Library of 1,4-Disubstituted 1,2,3-Triazole Analogs of Oxazolidinone RNA-Binding Agents. J. Comb. Chem. 2010, 12, 4, 491–496. doi:10.1021/cc100029y.
  2. ^ 2.0 2.1 2.2 Meng Xiang, Xiang Zhou, Ting-Rong Luo, Pei-Yi Wang, Li-Wei Liu, Zhong Li, Zhi-Bing Wu, and Song Yang. Design, Synthesis, Antibacterial Evaluation, and Induced Apoptotic Behaviors of Epimeric and Chiral 18β-Glycyrrhetinic Acid Ester Derivatives with an Isopropanolamine Bridge against Phytopathogens. J. Agric. Food Chem. 2019, 67, 48, 13212–13220. doi:10.1021/acs.jafc.9b06147.

拓展阅读

编辑
  • Steinmann, B. Acid curing of epoxides: an unexpected mechanism for the reaction of glycidyl esters with acids. Polymer Bulletin 22, 637–644 (1989). doi:10.1007/BF00718946