4-羟基苯甲醛
化合物
（重定向自对羟基苯甲醛）
4-羟基苯甲醛是一种有机化合物，化学式为C7H6O2，存在于天麻兰[1]、山珊瑚[2]和香荚兰中。它可由4-羟基苯甲醇的催化氧化反应制得。[3][4]它和乙酸酐反应，可以得到4-乙酰氧基苯甲醛。[5]
| 4-羟基苯甲醛 | |
|---|---|
| |
| |
| IUPAC名 4-Hydroxybenzaldehyde | |
| 别名 | 对羟基苯甲醛 |
| 识别 | |
| CAS号 | 123-08-0 
|
| PubChem | 126 |
| ChemSpider | 123 |
| SMILES |
|
| InChI |
|
| InChIKey | RGHHSNMVTDWUBI-UHFFFAOYAN |
| ChEBI | 17597 |
| DrugBank | DB03560 |
| KEGG | C00633 |
| 性质 | |
| 化学式 | C7H6O2 |
| 摩尔质量 | 122.12 g·mol−1 |
| 外观 | 浅黄色粉末 |
| 密度 | 1.226 ± 0.06 g/cm3 |
| 熔点 | 112—116 °C（385—389 K） |
| 沸点 | 310—311 °C（583—584 K） |
| 磁化率 | -78.0·10−6 cm3/mol |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Ha, J. H.; Lee, D. U.; Lee, J. T.; Kim, J. S.; Yong, C. S.; Kim, J. A.; Ha, J. S.; Huh, K. 4-Hydroxybenzaldehyde from Gastrodia elata B1. Is active in the antioxidation and GABAergic neuromodulation of the rat brain. Journal of Ethnopharmacology. 2000, 73 (1–2): 329–333. PMID 11025174. doi:10.1016/S0378-8741(00)00313-5.
- ^ Li, Y. M.; Zhou, Z. L.; Hong, Y. F. (title in Chinese) [Studies on the phenolic derivatives from Galeola faberi Rolfe]. Yao Xue Xue Bao = Acta Pharmaceutica Sinica. 1993, 28 (10): 766–771. PMID 8009989 （中文）.
- ^ SyedF. Adil, MohamedE. Assal, Mufsir Kuniyil, Mujeeb Khan, Mohammed Rafi Shaik, Abdulrahman Alwarthan, JoselitoP. Labis, Mohammed RafiqH. Siddiqui. Synthesis and comparative catalytic study of zinc oxide (ZnO x ) nanoparticles promoted MnCO 3 , MnO 2 and Mn 2 O 3 for selective oxidation of benzylic alcohols using molecular oxygen. Materials Express. 2017-04-01, 7 (2): 79–92 [2021-05-21]. ISSN 2158-5849. doi:10.1166/mex.2017.1357 （英语）.
- ^ Eduardo Buxaderas, Marilyn Graziano-Mayer, María Volpe, Gabriel Radivoy. Bimetallic Cu-Pd Nanoparticles Supported on Bio-silica as an Efficient Catalyst for Selective Aerobic Oxidation of Benzylic Alcohols. Synthesis. 2016-10-21, 49 (06): 1387–1393 [2021-05-21]. ISSN 0039-7881. doi:10.1055/s-0036-1588628. （原始内容存档于2018-06-02） （英语）.
- ^ Karol Kraszewski, Ireneusz Tomczyk, Aneta Drabinska, Krzysztof Bienkowski, Renata Solarska, Marcin Kalek. Mechanism of Iodine(III)‐Promoted Oxidative Dearomatizing Hydroxylation of Phenols: Evidence for a Radical‐Chain Pathway. Chemistry – A European Journal. 2020-09-04, 26 (50): 11584–11592 [2021-05-21]. ISSN 0947-6539. doi:10.1002/chem.202002026 （英语）.