樟脑醌
樟脑醌是一种有机化合物，化学式为C10H14O2，它在牙科材料中用作光引发剂。[2]它可由樟脑在乙酸中经二氧化硒氧化制得。[3]它可以被次氯酸钠进一步氧化为樟脑酸。[4]它的两个羰基(C=O)也能被氢化铝锂还原为羟基（C-OH）。[5]
| 樟脑醌 | |
|---|---|
| |
| IUPAC名 2,6-Bornanedione | |
| 别名 | Camphorquinone 6-Oxocamphor CQ CPQ |
| 识别 | |
| CAS号 | 10373-78-1 
|
| PubChem | 25208 |
| SMILES |
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| 性质 | |
| 化学式 | C10H14O2 |
| 摩尔质量 | 166.22 g·mol−1 |
| 熔点 | 196—198 °C（469—471 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Jarugu Narasimha Moorthy, Nidhi Singhal, Kalyan Senapati. Oxidative cleavage of vicinal diols: IBX can do what Dess–Martin periodinane (DMP) can. Org. Biomol. Chem. 2007, 5 (5): 767–771 [2022-04-10]. ISSN 1477-0520. doi:10.1039/B618135J （英语）.
- ^ Jakubiak, J.; Allonas, X.; Fouassier, J.P.; Sionkowska, A.; Andrzejewska, E.; Linden, L.Å.; Rabek, J.F. Camphorquinone–amines photoinitating systems for the initiation of free radical polymerization. Polymer. August 2003, 44 (18): 5219–5226. doi:10.1016/S0032-3861(03)00568-8.
- ^ Hongjin Chen, Wenyuan Wang, Jianjun Zhu, Yiying Han, Jian Liu. Electropolymerization of D-A type EDOT-based monomers consisting of camphor substituted quinoxaline unit for electrochromism with enhanced performance. Polymer. 2022-02, 240: 124485 [2022-04-10]. doi:10.1016/j.polymer.2021.124485 （英语）.
- ^ D. T. C. Yang, C. J. Zhang, P. P. Fu, G. W. Kabalka. Oxidation of α-Substituted Carbonyl Compounds to Carboxylic Acids in Aqueous Media Using Ultrasound. Synthetic Communications. 1997-05, 27 (9): 1601–1605 [2022-04-10]. ISSN 0039-7911. doi:10.1080/00397919708006098 （英语）.
- ^ Duggan, Andrew R.; Mciteka, Lulama P.; Lobb, Kevin A.; Kaye, Perry T. 1H NMR-based kinetic-mechanistic study of the intramolecular trans-esterification of 2-exo-3-exo-dihydroxybornane monoacrylate esters. South African Journal of Chemistry, 2013. 66: 140-144. ISSN 0379-4350.