用户:DoroWolf/沙盒/硫酸铝
| DoroWolf/沙盒/硫酸铝 | |
|---|---|
| |
| IUPAC名 Aluminium sulfate | |
| 识别 | |
| CAS号 | 10043-01-3  7784-31-8（八水）
|
| PubChem | 24850 |
| ChemSpider | 23233 |
| SMILES |
|
| InChI |
|
| InChIKey | DIZPMCHEQGEION-CYFPFDDLAS |
| EINECS | 233-135-0 |
| RTECS | BD1700000 |
| 性质 | |
| 化学式 | Al2(SO4)3 |
| 摩尔质量 | 无水：342.15 g/mol 八水：666.44 g·mol⁻¹ |
| 外观 | 白色结晶固体 吸湿性 |
| 密度 | 2.672 g/cm3（无水） 1.62 g/cm3（八水） |
| 熔点 | 770 °C（1043 K） |
| 溶解性（水） | 31.2 g/100 mL (0 °C) 36.4 g/100 mL (20 °C) 89.0 g/100 mL (100 °C) |
| 溶解性 | 微溶于醇，稀酸 |
| pKa | 3.3–3.6 |
| 磁化率 | −93.0×10−6 cm3/mol |
| 折光度n D |
1.47[1] |
| 结构 | |
| 晶体结构 | 单斜（八水） |
| 热力学 | |
| ΔfHm⦵298K | -3440 kJ/mol |
| 危险性 | |
| NFPA 704 |
 0
1
0
|
| PEL | 无[2] |
| 相关物质 | |
| 其他阳离子 | 硫酸镓 硫酸锰 |
| 相关化学品 | 见矾 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
硫酸铝是一种盐，化学式为Al2(SO4)3。它易溶于水，主要用作饮用水和废水处理厂净化以及造纸中的絮凝剂（通过中和电荷促进颗粒碰撞）。
生产
编辑实验室生产
编辑Aluminium sulfate may be made by adding aluminium hydroxide, Al(OH)3, to sulfuric acid, H2SO4: > + 3 H2SO4 → Al2(SO4)3 + 6 H2O or by heating aluminium metal in a sulfuric acid solution:
- 2 Al + 3 H2SO4 → Al2(SO4)3 + 3 H2↑
From alum schists
编辑The alum schists employed in the manufacture of aluminium sulfate are mixtures of iron pyrite, aluminium silicate and various bituminous substances, and are found in upper Bavaria, Bohemia, Belgium, and Scotland. These are either roasted or exposed to the weathering action of the air. In the roasting process, sulfuric acid is formed and acts on the clay to form aluminium sulfate, a similar condition of affairs being produced during weathering. The mass is now systematically extracted with water, and a solution of aluminium sulfate of specific gravity 1.16 is prepared. This solution is allowed to stand for some time (in order that any calcium sulfate and basic iron(III) sulfate may separate), and is then evaporated until iron(II) sulfate crystallizes on cooling; it is then drawn off and evaporated until it attains a specific gravity of 1.40. It is now allowed to stand for some time, and decanted from any sediment.[3]
From clays or bauxite
编辑In the preparation of aluminium sulfate from clays or from bauxite, the material is gently calcined, then mixed with sulfuric acid and water and heated gradually to boiling; if concentrated acid is used no external heat is generally required as the formation of aluminium sulfate is exothermic. It is allowed to stand for some time, and the clear solution is drawn off.
From cryolite
编辑When cryolite is used as the ore, it is mixed with calcium carbonate and heated. By this means, sodium aluminate is formed; it is then extracted with water and precipitated either by sodium bicarbonate or by passing a current of carbon dioxide through the solution. The precipitate is then dissolved in sulfuric acid.[3]
用途
编辑
Aluminium sulfate is sometimes used in the human food industry as a firming agent, where it takes on E number E520, and in animal feed as a bactericide. In the United States, the FDA lists it as "generally recognized as safe" with no limit on concentration.[4] Aluminium sulfate may be used as a deodorant, an astringent, or as a styptic for superficial shaving wounds.[5] Aluminium sulfate is used as a mordant in dyeing and printing textiles.
It is a common vaccine adjuvant and works "by facilitating the slow release of antigen from the vaccine depot formed at the site of inoculation."[5]
Aluminium sulfate is used in water purification and for chemical phosphorus removal from wastewater. It causes suspended impurities to coagulate into larger particles and then settle to the bottom of the container (or be filtered out) more easily. This process is called coagulation or flocculation. Research suggests that in Australia, aluminium sulfate used in this way in drinking water treatment is the primary source of hydrogen sulfide gas in sanitary sewer systems.[6] An improper and excess application incident in 1988 polluted the water supply of Camelford in Cornwall.
Aluminium sulfate has been used as a method of eutrophication remediation for shallow lakes. It works by reducing the phosphorus load in the lakes.[7][8]
When dissolved in a large amount of neutral or slightly alkaline water, aluminium sulfate produces a gelatinous precipitate of aluminium hydroxide, Al(OH)3. In dyeing and printing cloth, the gelatinous precipitate helps the dye adhere to the clothing fibers by rendering the pigment insoluble.
Aluminium sulfate is sometimes used to reduce the pH of garden soil, as it hydrolyzes to form the aluminium hydroxide precipitate and a dilute sulfuric acid solution. An example of what changing the pH level of soil can do to plants is visible when looking at Hydrangea macrophylla. The gardener can add aluminium sulfate to the soil to reduce the pH which in turn will result in the flowers of the Hydrangea turning a different color (blue). The aluminium is what makes the flowers blue; at a higher pH, the aluminium is not available to the plant.[9]
In the construction industry, it is used as waterproofing agent and accelerator in concrete. Another use is a foaming agent in fire fighting foam.
It can also be very effective as a molluscicide,[10] killing spanish slugs.
Mordants aluminium triacetate and aluminium sulfacetate can be prepared from aluminium sulfate, the product formed being determined by the amount of lead(II) acetate used:[11]
- Al
2(SO
4)
3 + 3 Pb(CH
3CO
2)
2 → 2 Al(CH
3CO
2)
3 + 3 PbSO
4
- Al
2(SO
4)
3 + 2 Pb(CH
3CO
2)
2 → Al
2SO
4(CH
3CO
2)
4 + 2 PbSO
4
化学反应
编辑The compound decomposes to γ-alumina and sulfur trioxide when heated between 580 and 900 °C. It combines with water forming hydrated salts of various compositions.
Aluminium sulfate reacts with sodium bicarbonate to which foam stabilizer has been added, producing carbon dioxide for fire-extinguishing foams:
- Al2(SO4)3 + 6 NaHCO3 → 3 Na2SO4 + 2 Al(OH)3 + 6 CO2
The carbon dioxide is trapped by the foam stabilizer and creates a thick foam which will float on top of hydrocarbon fuels and seal off access to atmospheric oxygen, smothering the fire. Chemical foam was unsuitable for use on polar solvents such as alcohol, as the fuel would mix with and break down the foam blanket. The carbon dioxide generated also served to propel the foam out of the container, be it a portable fire extinguisher or fixed installation using hoselines. Chemical foam is considered obsolete in the United States and has been replaced by synthetic mechanical foams, such as AFFF which have a longer shelf life, are more effective, and more versatile, although some countries such as Japan and India continue to use it.[来源请求]
参考资料
编辑- ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0-07-049439-8
- ^ 引用错误：没有为名为
PGCH的参考文献提供内容 - ^ 3.0 3.1 Chisholm 1911，第767页.
- ^ 21 CFR 182.1125, 2020-04-01 [2021-02-22]
- ^ 5.0 5.1 Compound Summary for CID 24850 - Aluminum Sulfate Anhydrous. PubChem.
- ^ Ilje Pikaar; Keshab R. Sharma; Shihu Hu; Wolfgang Gernjak; Jürg Keller; Zhiguo Yuan. Reducing sewer corrosion through integrated urban water management. Science. 2014, 345 (6198): 812–814. Bibcode:2014Sci...345..812P. PMID 25124439. S2CID 19126381. doi:10.1126/science.1251418.
- ^ Kennedy, Robert H.; Cook, G. Dennis. Control of Lake Phosphorus with Aluminum Sulfate: Dose Determination and Application Techniques. Journal of the American Water Resources Association. June 1982, 18 (3): 389–395. Bibcode:1982JAWRA..18..389K. ISSN 1093-474X. doi:10.1111/j.1752-1688.1982.tb00005.x.
- ^ Martyn, Huser, Brian J. Egemose, Sara Harper, Harvey Hupfer, Michael Jensen, Henning Pilgrim, Keith M. Reitzel, Kasper Rydin, Emil Futter. Longevity and effectiveness of aluminum addition to reduce sediment phosphorus release and restore lake water quality. Uppsala universitet, Limnologi. 2016. OCLC 1233676585.
- ^ Kari Houle. Blue or Pink - Which Color is Your Hydrangea. University of Illinois Extension. 2013-06-18 [2018-09-03].
- ^ Council, British Crop Protection; Society, British Ecological; Biologists, Association of Applied. Field margins: integrating agriculture and conservation : proceedings of a symposium organised by the British Crop Protection Council in association with the British Ecological Society and the Association of Applied Biologists and held at the University of Warwick, Coventry on 18–20 April 1994. British Crop Protection Council. 1994. ISBN 9780948404757 （英语）.
- ^ Georgievics, Von. The Chemical Technology of Textile Fibres – Their Origin, Structure, Preparation, Washing, Bleaching, Dyeing, Printing and Dressing. Read Books. 2013. ISBN 9781447486121. （原始内容存档于2017-12-05）.
- Chisholm, Hugh (编). Aluminium. Encyclopædia Britannica 1 (第11版). London: Cambridge University Press: 767. 1911.
- Pauling, Linus. General Chemistry
. W.H. Freeman: San Francisco. 1970. ISBN 978-0-486-65622-9.
