乙酰乙酸环己酯
乙酰乙酸环己酯是一种有机化合物，化学式为C10H16O3。它可由乙酰乙酸甲酯或乙酰乙酸乙酯在催化下和环己醇反应制得。[3][4]它和苯乙炔在碳酸银、乙酸钾存在下反应，可以得到2-甲基-5-苯基-3-呋喃甲酸环己酯。[5]它和氯化镁反应，形成配合物。[6]
| 乙酰乙酸环己酯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 6947-02-0 
|
| 性质 | |
| 化学式 | C10H16O3 |
| 摩尔质量 | 184.23 g·mol−1 |
| 熔点 | 190—192 °C（463—465 K）[1] |
| 沸点 | 130—131 °C（403—404 K）（16 torr）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
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- ^ Alfred R. Bader, Lowell O. Cummings, Henry A. Vogel. Transesterification. I. β-Keto Esters. Journal of the American Chemical Society. 1951-09, 73 (9): 4195–4197 [2021-11-20]. ISSN 0002-7863. doi:10.1021/ja01153a045. （原始内容存档于2021-11-20） （英语）.
- ^ Benjaram M. Reddy, Vangala R. Reddy, Basude Manohar. Mo-ZrO 2 Solid Acid Catalyst For Transesterification of β-Ketoesters. Synthetic Communications. 1999-04, 29 (7): 1235–1239 [2021-11-20]. ISSN 0039-7911. doi:10.1080/00397919908086095 （英语）.
- ^ G.C.M. Kondaiah, L. Amarnath Reddy, K. Srihari Babu, V.M. Gurav, K.G. Huge, R. Bandichhor, P. Pratap Reddy, A. Bhattacharya, R. Vijaya Anand. Boric acid: an efficient and environmentally benign catalyst for transesterification of ethyl acetoacetate. Tetrahedron Letters. 2008-01, 49 (1): 106–109 [2021-11-20]. doi:10.1016/j.tetlet.2007.11.008. （原始内容存档于2020-10-13） （英语）.
- ^ Chuan He, Sheng Guo, Jie Ke, Jing Hao, Huan Xu, Hongyi Chen, Aiwen Lei. Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans. Journal of the American Chemical Society. 2012-04-04, 134 (13): 5766–5769 [2021-11-20]. ISSN 0002-7863. doi:10.1021/ja301153k. （原始内容存档于2021-11-20） （英语）.
- ^ L.I. Koval, V.I. Dzyuba, V.V. Bon, O.L. Ilnitska, V.I. Pekhnyo. Synthesis and structure of anhydrous complexes of magnesium(II) with β-ketoesters of higher alcohols. Polyhedron. 2009-09, 28 (13): 2698–2702 [2021-11-20]. doi:10.1016/j.poly.2009.05.034. （原始内容存档于2022-03-22） （英语）.