乙酰乙酸環己酯
乙酰乙酸環己酯是一種有機化合物，化學式為C10H16O3。它可由乙酰乙酸甲酯或乙酰乙酸乙酯在催化下和環己醇反應製得。[3][4]它和苯乙炔在碳酸銀、乙酸鉀存在下反應，可以得到2-甲基-5-苯基-3-呋喃甲酸環己酯。[5]它和氯化鎂反應，形成配合物。[6]
| 乙酰乙酸環己酯 | |
|---|---|
| |
| 識別 | |
| CAS號 | 6947-02-0 
|
| 性質 | |
| 化學式 | C10H16O3 |
| 摩爾質量 | 184.23 g·mol−1 |
| 熔點 | 190—192 °C（463—465 K）[1] |
| 沸點 | 130—131 °C（403—404 K）（16 torr）[2] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Ebrahimzadeh, M. A.; Pourmorad, F.; Mahmoudi, M. Preparation of some new analgesic dihydropyridine derivatives and their SAR studies. QSAR and Molecular Modelling in Rational Design of Bioactive Molecules, Proceedings of the European Symposium on Structure-Activity Relationships (QSAR) and Molecular Modelling, 15th, Istanbul, Turkey, Sept. 5-10, 2004 [Conference]. 2006. pp 164-165. ISBN 975-00782-0-9.
- ^ Alfred R. Bader, Lowell O. Cummings, Henry A. Vogel. Transesterification. I. β-Keto Esters. Journal of the American Chemical Society. 1951-09, 73 (9): 4195–4197 [2021-11-20]. ISSN 0002-7863. doi:10.1021/ja01153a045. （原始內容存檔於2021-11-20） （英語）.
- ^ Benjaram M. Reddy, Vangala R. Reddy, Basude Manohar. Mo-ZrO 2 Solid Acid Catalyst For Transesterification of β-Ketoesters. Synthetic Communications. 1999-04, 29 (7): 1235–1239 [2021-11-20]. ISSN 0039-7911. doi:10.1080/00397919908086095 （英語）.
- ^ G.C.M. Kondaiah, L. Amarnath Reddy, K. Srihari Babu, V.M. Gurav, K.G. Huge, R. Bandichhor, P. Pratap Reddy, A. Bhattacharya, R. Vijaya Anand. Boric acid: an efficient and environmentally benign catalyst for transesterification of ethyl acetoacetate. Tetrahedron Letters. 2008-01, 49 (1): 106–109 [2021-11-20]. doi:10.1016/j.tetlet.2007.11.008. （原始內容存檔於2020-10-13） （英語）.
- ^ Chuan He, Sheng Guo, Jie Ke, Jing Hao, Huan Xu, Hongyi Chen, Aiwen Lei. Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans. Journal of the American Chemical Society. 2012-04-04, 134 (13): 5766–5769 [2021-11-20]. ISSN 0002-7863. doi:10.1021/ja301153k. （原始內容存檔於2021-11-20） （英語）.
- ^ L.I. Koval, V.I. Dzyuba, V.V. Bon, O.L. Ilnitska, V.I. Pekhnyo. Synthesis and structure of anhydrous complexes of magnesium(II) with β-ketoesters of higher alcohols. Polyhedron. 2009-09, 28 (13): 2698–2702 [2021-11-20]. doi:10.1016/j.poly.2009.05.034. （原始內容存檔於2022-03-22） （英語）.