六氟环丙烷
化合物
六氟环丙烷是一种有机化合物，化学式为C3F6。它和碘于155 °C反应，可以得到1,1,2,2,3,3-六氟-1,3-二碘丙烷。[3]和一氯化碘反应，生成开环的氯碘代产物、二氯代产物和二碘代产物。[4]它和其它卤素或互卤化物可以发生类似反应。[5]
| 六氟环丙烷 | |
|---|---|
| |
| 别名 | 全氟环丙烷 C 216 |
| 识别 | |
| CAS号 | 931-91-9 
|
| 性质 | |
| 密度 | 1.62±0.1 g·cm−3（20 °C）[1] |
| 沸点 | −28 °C（245 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-05-11].
- ^ Benning, Anthony F.; Downing, Frederick B.; Park, Joseph D. Pyrolysis of tetrafluoroethylene polymer, 1946. US 2394581.
- ^ Smith, Michael B.; Nikonov, George. Iodine. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2013. 1-16. ISBN 978-0-470-84289-8.
- ^ Zhen-Yu Yang. Preparation of Highly Fluorinated Cyclopropanes and Ring-Opening Reactions with Halogens †. The Journal of Organic Chemistry. 2003-05, 68 (11): 4410–4416 [2020-05-11]. ISSN 0022-3263. doi:10.1021/jo030014y （英语）.
- ^ Zhen-Yu Yang, Paul J. Krusic, Bruce E. Smart. Ring-Opening Reactions of Fluorocyclopropanes with Halogens: A General and Useful Route to 1,3-Dihalofluoropropane Derivatives. Journal of the American Chemical Society. 1995-05, 117 (19): 5397–5398 [2020-05-11]. ISSN 0002-7863. doi:10.1021/ja00124a038 （英语）.