六氟环丙烷

化合物

六氟环丙烷是一种有机化合物,化学式为C3F6。它和于155 °C反应,可以得到1,1,2,2,3,3-六氟-1,3-二碘丙烷。[3]一氯化碘反应,生成开环的氯碘代产物、二氯代产物和二碘代产物。[4]它和其它卤素或互卤化物可以发生类似反应。[5]

六氟环丙烷
别名 全氟环丙烷
C 216
识别
CAS号 931-91-9  checkY
性质
密度 1.62±0.1 g·cm−3(20 °C)[1]
沸点 −28 °C(245 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-05-11].
  2. ^ Benning, Anthony F.; Downing, Frederick B.; Park, Joseph D. Pyrolysis of tetrafluoroethylene polymer, 1946. US 2394581.
  3. ^ Smith, Michael B.; Nikonov, George. Iodine. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2013. 1-16. ISBN 978-0-470-84289-8.
  4. ^ Zhen-Yu Yang. Preparation of Highly Fluorinated Cyclopropanes and Ring-Opening Reactions with Halogens †. The Journal of Organic Chemistry. 2003-05, 68 (11): 4410–4416 [2020-05-11]. ISSN 0022-3263. doi:10.1021/jo030014y (英语). 
  5. ^ Zhen-Yu Yang, Paul J. Krusic, Bruce E. Smart. Ring-Opening Reactions of Fluorocyclopropanes with Halogens: A General and Useful Route to 1,3-Dihalofluoropropane Derivatives. Journal of the American Chemical Society. 1995-05, 117 (19): 5397–5398 [2020-05-11]. ISSN 0002-7863. doi:10.1021/ja00124a038 (英语).