2-乙基己酸铬
化合物
2-乙基己酸铬是一种配位化合物，化学式为C24H45CrO6。它可由CrCl3(THF)3、NaH和2-乙基己酸在无水四氢呋喃中反应得到。[2]它和2,5-二甲基吡咯一起可以催化乙烯三聚。[3]
| Chromium(III) 2-ethylhexanoate | |
|---|---|
_2-ethylhexanoate.svg)
| |
| IUPAC名 Chromium(3+) 2-ethylhexanoate | |
| 别名 | Chromium(3+) tris(2-ethylhexanoate) 2-Ethylhexanoic acid chromium(III) salt AR-1I2320 CID103012 |
| 识别 | |
| CAS号 | 3444-17-5 
|
| PubChem | 103012 |
| ChemSpider | 93064 |
| SMILES |
|
| EINECS | 222-357-3 |
| 性质 | |
| 化学式 | C24H45CrO6 |
| 摩尔质量 | 481.6 g/mol g·mol⁻¹ |
| 外观 | 绿色 |
| 密度 | 1.01 g/cm3 |
| 溶解性（水） | soluble in mineral spirits |
| 危险性 | |
GHS危险性符号 
| |
| GHS提示词 | 警告 |
| H-术语 | H302, H312, H315, H317, H319, H361 |
| P-术语 | P201, P202, P261, P264, P270, P272, P280, P281, P301+312, P302+352, P305+351+338, P308+313, P312, P321 |
| 主要危害 | Harmful by inhalation, in contact with skin and if swallowed, Irritating to eyes, respiratory system and skin |
| PEL | TWA 1 mg/m3[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ NIOSH Pocket Guide to Chemical Hazards. #0141. NIOSH.
- ^ Venderbosch, Bas; Oudsen, Jean-Pierre H.; Wolzak, Lukas A.; Martin, David J. ; Korstanje, Ties J.; Tromp, Moniek. ACS Catalysis (2019), 9(2), 1197-1210. doi:10.1021/acscatal.8b03414.
- ^ Naji-Rad, Ebtehal; Gimferrer, Martí; Bahri-Laleh, Naeimeh; Nekoomanesh-Haghighi, Mehdi; Jamjah, Roghieh; Poater, Albert. Exploring Basic Components Effect on the Catalytic Efficiency of Chevron-Phillips Catalyst in Ethylene Trimerization. Catalysts. 24 May 2018, 8 (6): 224. doi:10.3390/catal8060224
. hdl:10256/15519 .
