丁二硫醚
化合物
丁二硫醚或二丁基二硫是一种有机化合物，化学式为C8H18S2。它可由正丁硫醇的氧化反应制得。[4]它在二氯甲烷中可以被间氯过氧苯甲酸氧化，生成丁基硫代亚磺酸-S-丁酯。[5]它和溴化苄、锌在三氯化铝催化下反应，可以得到苄基丁硫醚。[6]
| 丁二硫醚 | |
|---|---|
| |
| 别名 | 二丁基二硫 二正丁基二硫 二正丁基二硫醚 |
| 识别 | |
| CAS号 | 629-45-8 
|
| 性质 | |
| 化学式 | C8H18S2 |
| 摩尔质量 | 178.36 g·mol⁻¹ |
| 密度 | 0.930 g·cm−3（20 °C）[1] |
| 熔点 | 116—118 °C（389—391 K）[2] |
| 沸点 | 228—230 °C（501—503 K）[3] |
| 相关物质 | |
| 相关化学品 | 丁硫醚 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Gilman, Henry; Smith, Lloyd E.; Parker, Harold H. THE CONSTITUTION OF DISULFOXIDES. Journal of the American Chemical Society (American Chemical Society (ACS)). 1925, 47 (3): 851–860. ISSN 0002-7863. doi:10.1021/ja01680a037.
- ^ Habib Firouzabadi, Daryoush Mohajer, Mohsen Entezari-Moghadam. Barium Ferrate Monohydrate BaFeO 4 ·H 2 O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions. Bulletin of the Chemical Society of Japan. 1988-06, 61 (6): 2185–2189 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.61.2185. （原始内容存档于2021-12-02） （英语）.
- ^ Hisashi Fujihara, Ryouichi Akaishi, Naomichi Furukawa. A Mild, High-Yield Conversion of Thiols into Disulfides Using Disulfide Dication Salt: A New Redox System. Bulletin of the Chemical Society of Japan. 1989-02, 62 (2): 616–617 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.62.616. （原始内容存档于2021-12-02） （英语）.
- ^ Abhinandan D. Hudwekar, Praveen K. Verma, Jaspreet Kour, Shilpi Balgotra, Sanghapal D. Sawant. Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides: Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazole. European Journal of Organic Chemistry. 2019-02-14, 2019 (6): 1242–1250 [2021-12-10]. doi:10.1002/ejoc.201801610 （英语）.
- ^ Jinyue Su, Yatao Qiu, Kun Ma, Yiwu Yao, Zhen Wang, Xianling Li, Dayong Zhang, Zhengchao Tu, Sheng Jiang. Design, synthesis, and biological evaluation of largazole derivatives: alteration of the zinc-binding domain. Tetrahedron. 2014-10, 70 (42): 7763–7769 [2021-12-10]. doi:10.1016/j.tet.2014.05.078. （原始内容存档于2018-07-01） （英语）.
- ^ M. M. Lakouraj, B. Movassagh, Z. Fadaei. SYNTHESIS OF ORGANIC SULFIDES VIA Zn/AlCl 3 SYSTEM IN AQUEOUS MEDIA. Synthetic Communications. 2002-01, 32 (8): 1237–1242 [2021-12-10]. ISSN 0039-7911. doi:10.1081/SCC-120003615 （英语）.