八氟合氙(VI)酸铯

八氟合氙(VI)酸铯是一种配位化合物,化学式为Cs2XeF8,分子中的XeF82-具有D4d对称性。[3]它可由氟化铯四氟化氙于100 °C反应得到[4],或通过CsXeF7的分解生成。[5]

八氟合氙(VI)酸铯
识别
CAS号 17501-71-2  checkY
性质
化学式 Cs2XeF8
外观 奶油色[1]
熔点 400 °C(分解)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Complex compounds of xenon hexafluoride with the alkali fluorides. Journal of Inorganic and Nuclear Chemistry, 1966. 28 (11). doi:10.1016/0022-1902(66)80380-9
  2. ^ Kiselev, Yu. M.; Fadeeva, N. E.; Popov, A. I.; Korobov, M. V.; Nikulin, V. V.; Spitsyn, V. I. Thermal stability of alkali metal hexafluoroxenates(IV). Doklady Akademii Nauk SSSR, 1987. 295 (2): 378-381. ISSN 0002-3264.
  3. ^ Karl O. Christe and William W. Wilson. Perfluoroammonium and alkali-metal salts of the heptafluoroxenon(VI) and octafluoroxenon(VI) anions. Inorg. Chem. 1982, 21, 12, 4113–4117. doi:10.1021/ic00142a001.
  4. ^ Kiselev, Yu. M.; Goryachenkov, S. A.; Martynenko, L. I.; Spitsyn, V. I. Interaction of lower xenon fluorides with alkali metal fluorides. Doklady Akademii Nauk SSSR (1984), 278(4), 881-885. ISSN 0002-3264
  5. ^ Peacock R D, Selig H, Sheft I. Complex fluoroxenates(VI). Proceedings of the Chemical Society, London. 1964. 285. ISSN 0369-8718