1,8-萘啶
化合物
1,8-萘啶（英语：1,8-Naphthyridine，也称为1,8-二氮杂萘）是萘啶（二氮杂萘，分子式C8H6N2）的同分异构体之一[2][3]。其衍生物有依诺沙星、萘啶酸、曲伐沙星等。1,8-萘啶在配位化学中是双核配体，即与两个金属原子配位的配体。[4][5]
| 1,8-萘啶 | |
|---|---|
| |
| IUPAC名 1,8-Naphthyridine[1] | |
| 识别 | |
| CAS号 | 254-60-4 |
| PubChem | 136069 |
| ChemSpider | 119846 |
| SMILES |
|
| Beilstein | 109347 |
| Gmelin | 27124 |
| EINECS | 675-799-8 |
| ChEBI | 36628 |
| 性质 | |
| 化学式 | C8H6N2 |
| 摩尔质量 | 130.15 g·mol−1 |
| 外观 | 黄色固体 |
| 密度 | 1.359 g/cm3 |
| 熔点 | 98—99 °C（208—210 °F；371—372 K） |
| 危险性 | |
GHS危险性符号
| |
| GHS提示词 | Warning |
| H-术语 | H315, H319, H335 |
| P-术语 | P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ International Union of Pure and Applied Chemistry. Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. 2014: 212. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069.
- ^ Litvinov, Victor P.; Roman, Sergey V.; Dyachenko, Vladimir D. Naphthyridines. Structure, Physicochemical Properties and General Methods of Synthesis. Russian Chemical Reviews. 2000, 69 (3): 201–220. Bibcode:2000RuCRv..69..201L. S2CID 250827396. doi:10.1070/RC2000v069n03ABEH000553.
- ^ Dapporto, P.; Ghilardi, C. A.; Mealli, C.; Orlandini, A.; Pacinotti, S. Low-Temperature (163 K) Structure of 1,8-Naphthyridine, C8H6N2. Acta Crystallographica Section C Crystal Structure Communications. 1984, 40 (5): 891–894. doi:10.1107/S0108270184006144.
- ^ Hua, Shao-An; Liu, Isiah Po-Chun; Hasanov, Hasan; Huang, Gin-Chen; Ismayilov, Rayyat Huseyn; Chiu, Chien-Lan; Yeh, Chen-Yu; Lee, Gene-Hsiang; Peng, Shie-Ming. Probing the electronic communication of linear heptanickel and nonanickel string complexes by utilizing two redox-active [Ni2(napy)4]3+ moieties. Dalton Transactions. 2010, 39 (16): 3890–6. PMID 20372713. doi:10.1039/b923125k.
- ^ Bera, Jitendra K.; Sadhukhan, Nabanita; Majumdar, Moumita. 1,8-Naphthyridine Revisited: Applications in Dimetal Chemistry. European Journal of Inorganic Chemistry. 2009, 2009 (27): 4023–4038. doi:10.1002/ejic.200900312.