1-溴十一烷
化合物
1-溴十一烷是一种有机化合物，化学式为C11H23Br。它可由1-十一醇和溴在三苯基膦的存在下于二氯甲烷中反应得到。[4]1-十二烷酸和溴、氧化汞在四氯化碳中回流反应，也可得到1-溴十一烷。[5]它和叠氮化钠在DMF中反应，可以得到正十一烷基叠氮化物。[6]它和三苯基膦反应，得到季𬭸盐十一烷基三苯基溴化𬭸。[7]
| 1-溴十一烷 | |
|---|---|
| |
| 别名 | 1-溴正十一烷 正十一烷基溴 |
| 识别 | |
| CAS号 | 693-67-4 
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| SMILES |
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| 性质 | |
| 化学式 | C11H23Br |
| 摩尔质量 | 235.2 g·mol−1 |
| 密度 | 1.0521 g·cm−3（20 °C）[1] |
| 熔点 | −9 °C（264 K）[2] |
| 沸点 | 124.7—125 °C（397.8—398.1 K）（12 Torr）[2] 137—138 °C（410—411 K）（18 Torr）[3] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ G. R. Yohe, Roger Adams. CYCLOPENTYL ALKYL ACETIC ACIDS AND OMEGA-CYCLOPENTYLETHYL ALKYL ACETIC ACIDS AND THEIR BACTERICIDAL ACTION TOWARD B. LEPRAE. XI 1. Journal of the American Chemical Society. 1928-05, 50 (5): 1503–1508 [2021-01-14]. ISSN 0002-7863. doi:10.1021/ja01392a042 （英语）.
- ^ 2.0 2.1 Takao Kaneko, Taihei Ainazaki. On the Preparations and the Melting Points of n Alkyl-bromides. Nippon kagaku zassi. 1955, 76 (3): 281–284 [2021-01-14]. ISSN 0369-5387. doi:10.1246/nikkashi1948.76.281.
- ^ P. B. Lumb, J. C. Smith. 982. Higher aliphatic compounds. Part X. A synthesis of tariric and petroselinic acids. Journal of the Chemical Society (Resumed). 1952: 5032 [2021-01-14]. ISSN 0368-1769. doi:10.1039/jr9520005032 （英语）.
- ^ Túlio M. Nunes, Sidnei Mateus, Arodi P. Favaris, Mônica F. Z. J. Amaral, Lucas G. von Zuben, Giuliano C. Clososki, José M. S. Bento, Benjamin P. Oldroyd, Ricardo Silva, Ronaldo Zucchi, Denise B. Silva, Norberto P. Lopes. Queen signals in a stingless bee: suppression of worker ovary activation and spatial distribution of active compounds. Scientific Reports. 2015-05, 4 (1) [2021-01-14]. ISSN 2045-2322. PMC 4264003
. PMID 25502598. doi:10.1038/srep07449. （原始内容存档于2022-03-04） （英语）.
- ^ S. Ravi, K. M. Mathew, V. K. P. Unny, N. Sivaprasad. A facile synthesis of high specific activity sodium [1-14C] lauryl sulphate under microwave irradiation. Journal of Labelled Compounds and Radiopharmaceuticals. 2005-12, 48 (14): 1055–1058 [2021-01-14]. ISSN 0362-4803. doi:10.1002/jlcr.966 （英语）.
- ^ Christiane Lang, Kai Pahnke, Claude Kiefer, Anja S. Goldmann, Peter W. Roesky, Christopher Barner-Kowollik. Consecutive modular ligation as an access route to palladium containing polymers. Polymer Chemistry. 2013, 4 (21): 5456 [2021-01-14]. ISSN 1759-9954. doi:10.1039/c3py00648d （英语）.
- ^ Qian Yu, Zhu-Jun Yao, Xiao-Guang Chen, Yu-Lin Wu. Total Synthesis of (10 R )- and (10 S )-Corossolin: Determination of the Stereochemistry at C-10 of the Natural Corossolin and the Differential Toxicity toward Cancer Cells Caused by the Configuration at C-10. The Journal of Organic Chemistry. 1999-04, 64 (7): 2440–2445 [2021-01-14]. ISSN 0022-3263. doi:10.1021/jo982241j （英语）.
