1-溴十一烷
化合物
1-溴十一烷是一種有機化合物，化學式為C11H23Br。它可由1-十一醇和溴在三苯基膦的存在下於二氯甲烷中反應得到。[4]1-十二烷酸和溴、氧化汞在四氯化碳中回流反應，也可得到1-溴十一烷。[5]它和疊氮化鈉在DMF中反應，可以得到正十一烷基疊氮化物。[6]它和三苯基膦反應，得到季鏻鹽十一烷基三苯基溴化鏻。[7]
| 1-溴十一烷 | |
|---|---|
| |
| 別名 | 1-溴正十一烷 正十一烷基溴 |
| 識別 | |
| CAS號 | 693-67-4 
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| SMILES |
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| 性質 | |
| 化學式 | C11H23Br |
| 摩爾質量 | 235.2 g·mol−1 |
| 密度 | 1.0521 g·cm−3（20 °C）[1] |
| 熔點 | −9 °C（264 K）[2] |
| 沸點 | 124.7—125 °C（397.8—398.1 K）（12 Torr）[2] 137—138 °C（410—411 K）（18 Torr）[3] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ G. R. Yohe, Roger Adams. CYCLOPENTYL ALKYL ACETIC ACIDS AND OMEGA-CYCLOPENTYLETHYL ALKYL ACETIC ACIDS AND THEIR BACTERICIDAL ACTION TOWARD B. LEPRAE. XI 1. Journal of the American Chemical Society. 1928-05, 50 (5): 1503–1508 [2021-01-14]. ISSN 0002-7863. doi:10.1021/ja01392a042 （英語）.
- ^ 2.0 2.1 Takao Kaneko, Taihei Ainazaki. On the Preparations and the Melting Points of n Alkyl-bromides. Nippon kagaku zassi. 1955, 76 (3): 281–284 [2021-01-14]. ISSN 0369-5387. doi:10.1246/nikkashi1948.76.281.
- ^ P. B. Lumb, J. C. Smith. 982. Higher aliphatic compounds. Part X. A synthesis of tariric and petroselinic acids. Journal of the Chemical Society (Resumed). 1952: 5032 [2021-01-14]. ISSN 0368-1769. doi:10.1039/jr9520005032 （英語）.
- ^ Túlio M. Nunes, Sidnei Mateus, Arodi P. Favaris, Mônica F. Z. J. Amaral, Lucas G. von Zuben, Giuliano C. Clososki, José M. S. Bento, Benjamin P. Oldroyd, Ricardo Silva, Ronaldo Zucchi, Denise B. Silva, Norberto P. Lopes. Queen signals in a stingless bee: suppression of worker ovary activation and spatial distribution of active compounds. Scientific Reports. 2015-05, 4 (1) [2021-01-14]. ISSN 2045-2322. PMC 4264003
. PMID 25502598. doi:10.1038/srep07449. （原始內容存檔於2022-03-04） （英語）.
- ^ S. Ravi, K. M. Mathew, V. K. P. Unny, N. Sivaprasad. A facile synthesis of high specific activity sodium [1-14C] lauryl sulphate under microwave irradiation. Journal of Labelled Compounds and Radiopharmaceuticals. 2005-12, 48 (14): 1055–1058 [2021-01-14]. ISSN 0362-4803. doi:10.1002/jlcr.966 （英語）.
- ^ Christiane Lang, Kai Pahnke, Claude Kiefer, Anja S. Goldmann, Peter W. Roesky, Christopher Barner-Kowollik. Consecutive modular ligation as an access route to palladium containing polymers. Polymer Chemistry. 2013, 4 (21): 5456 [2021-01-14]. ISSN 1759-9954. doi:10.1039/c3py00648d （英語）.
- ^ Qian Yu, Zhu-Jun Yao, Xiao-Guang Chen, Yu-Lin Wu. Total Synthesis of (10 R )- and (10 S )-Corossolin: Determination of the Stereochemistry at C-10 of the Natural Corossolin and the Differential Toxicity toward Cancer Cells Caused by the Configuration at C-10. The Journal of Organic Chemistry. 1999-04, 64 (7): 2440–2445 [2021-01-14]. ISSN 0022-3263. doi:10.1021/jo982241j （英語）.
