2,2-二(4-环氧乙基甲氧基环己基)丙烷

化合物

2,2-二(4-环氧乙基甲氧基环己基)丙烷是一种有机化合物,化学式为C21H36O4。它可用于制备抗静电树脂[2]

2,2-二(4-环氧乙基甲氧基环己基)丙烷
IUPAC名
2-[[4-[2-[4-(oxiran-2-ylmethoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxymethyl]oxirane
英文名 2,2-bis[4-(2,3-epoxypropoxy)cyclohexyl]propane
别名 2,2-双[4-(2,3-环氧丙氧基)环己基]丙烷
氢化双酚A二缩水甘油酯
识别
CAS号 13410-58-7  checkY
PubChem 114514
SMILES
 
  • CC(C)(C1CCC(CC1)OCC2CO2)C3CCC(CC3)OCC4CO4
InChI
 
  • 1S/C21H36O4/c1-21(2,15-3-7-17(8-4-15)22-11-19-13-24-19)16-5-9-18(10-6-16)23-12-20-14-25-20/h15-20H,3-14H2,1-2H3
InChIKey GZPRASLJQIBVDP-UHFFFAOYSA-N
性质
化学式 C21H36O4
摩尔质量 352.51 g·mol−1
密度 1.07±0.1 g·cm−3[1]
溶解性 0.0012 g(25 °C)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

合成

编辑

2,2-二(4-环氧乙基甲氧基环己基)丙烷可由2,2-二(4-烯丙氧基环己基)丙烷和3-氯过氧苯甲酸反应制得。[3]2,2-二(4-环氧乙基甲氧基苯基)丙烷英语Bisphenol A diglycidyl ether二氧化钌的催化下加氢,也能得到该化合物。[4]

参考文献

编辑
  1. ^ 1.0 1.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-08-27].
  2. ^ Enjo, Naoki; Nomura, Kazukiyo. Antistatic resin composition capable of forming molded product having excellent antistatic performance, water wiping resistance and flame retardancy. 2021 JP 2021102685 A.
  3. ^ Klemarczyk, Philip; Messana, Andrew. New epoxy monomers for reworkable flipchip underfill adhesives - part 2. Proceedings of the Annual Meeting of the Adhesion Society. 2012, 35th: a82/1–a82/3. ISSN 1086-9506 (英语). 
  4. ^ Hara, Yoshinori; Inagaki, Hiroko. Selective Hydrogenation of Aromatic Compounds Containing Epoxy Group over Rh/Graphite. Chemistry Letters (The Chemical Society of Japan). 2002, 31 (11): 1116–1117. ISSN 0366-7022. doi:10.1246/cl.2002.1116 (英语). 

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编辑