乙酰丙酮釹

乙酰丙酮釹
英文名	Neodymium acetylacetonate
識別
CAS號	14589-38-9
性質
化學式	C15H21NdO6
摩爾質量	441.57 g·mol−1
外觀	粉色粉末
熔點	150 °C（423 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

乙酰丙酮釹是一種配位化合物，化學式為Nd(C₅H₇O₂)₃，或簡寫為Nd(acac)₃，它的不穩定常數（logY_n）分別為2.89、4.15和5.26（對應n=1, 2, 3）。^[2]它可由三烷氧基釹和乙酰丙酮反應製得，^[3]或通過金屬釹在乙酰丙酮中電解得到。^[4]它的二水合物和羰基錸配合物Re(CO)₃X(4,4'-bipy)（X=Cl, Br）反應，可以得到Re(CO)₃X(4,4'-bipy)Nd(acac)₃。^[5]

參考文獻

^ ^1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始內容存檔於2021-10-17）.
^ N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始內容存檔於2018-06-24）（英語）.
^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
^ Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.
^ Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄文）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

[Pierson-1] 1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始內容存檔於2021-10-17）.

[2] N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始內容存檔於2018-06-24）（英語）.

[3] Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.

[4] Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.

[5] Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄文）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

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