1,16-二溴十六烷

化合物

1,16-二溴十六烷是一種有機溴化合物,化學式為C16H32Br2。1,16-二溴十六烷可由NBS(或四溴化碳[3])和1,16-十六烷二醇在三苯基膦的存在下反應製得。[4]它和碘化鈉丙酮中回流,可以得到1,16-二碘十六烷[5]它和氰化鈉二甲基亞碸中加熱反應,得到1,18-十八烷二腈。[6]

1,16-二溴十六烷
英文名 1,16-dibromohexadecane
別名 1,16-二溴代十六烷
識別
CAS號 45223-18-5  checkY
SMILES
 
  • BrCCCCCCCCCCCCCCCCBr
性質
化學式 C16H32Br2
摩爾質量 384.23 g·mol−1
熔點 53.5—55 °C(326.6—328.1 K)[1]
57—58 °C(330—331 K)[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ R.G. Woolford. THE ELECTROLYSIS OF ω-BROMOCARBOXYLIC ACIDS. Canadian Journal of Chemistry. 1962-09-01, 40 (9): 1846–1850 [2020-11-16]. ISSN 0008-4042. doi:10.1139/v62-280 (英語). 
  2. ^ Alexander K.L. Yuen, Falk Heinroth, Antony J. Ward, Anthony F. Masters, Thomas Maschmeyer. Novel bis(methylimidazolium)alkane bolaamphiphiles as templates for supermicroporous and mesoporous silicas. Microporous and Mesoporous Materials. 2012-01, 148 (1): 62–72 [2020-11-16]. doi:10.1016/j.micromeso.2011.06.036. (原始內容存檔於2018-06-11) (英語). 
  3. ^ Jaejun Lee, Vivian M. Lau, Yi Ren, Christopher M. Evans, Jeffrey S. Moore, Nancy R. Sottos. Effect of Polymerized Ionic Liquid Structure and Morphology on Shockwave Energy Dissipation. ACS Macro Letters. 2019-04-26: 535–539 [2020-11-16]. ISSN 2161-1653. doi:10.1021/acsmacrolett.9b00133. (原始內容存檔於2019-06-07) (英語). 
  4. ^ Blanka E. Janicek, Joshua G. Hinman, Jordan J. Hinman, Sang hyun Bae, Meng Wu, Jacob Turner, Huei-Huei Chang, Eugene Park, Rachel Lawless, Kenneth S. Suslick, Catherine J. Murphy, Pinshane Y. Huang. Quantitative Imaging of Organic Ligand Density on Anisotropic Inorganic Nanocrystals. Nano Letters. 2019-09-11, 19 (9): 6308–6314 [2020-11-16]. ISSN 1530-6984. doi:10.1021/acs.nanolett.9b02434. (原始內容存檔於2020-10-06) (英語). 
  5. ^ Javier Castilla, Rocío Rísquez, Katsumi Higaki, Eiji Nanba, Kousaku Ohno, Yoshiyuki Suzuki, Yolanda Díaz, Carmen Ortiz Mellet, José M. García Fernández, Sergio Castillón. Conformationally-locked N-glycosides: Exploiting long-range non-glycone interactions in the design of pharmacological chaperones for Gaucher disease. European Journal of Medicinal Chemistry. 2015-01, 90: 258–266 [2020-11-16]. doi:10.1016/j.ejmech.2014.11.002. (原始內容存檔於2020-09-23) (英語). 
  6. ^ Michèle Calas, Mahama Ouattara, Gilles Piquet, Zyta Ziora, Y. Bordat, Marie L. Ancelin, Roger Escale, Henri Vial. Potent Antimalarial Activity of 2-Aminopyridinium Salts, Amidines, and Guanidines. Journal of Medicinal Chemistry. 2007-12, 50 (25): 6307–6315 [2020-11-16]. ISSN 0022-2623. doi:10.1021/jm0704752 (英語).