烯丙胺鹽酸鹽
化合物
烯丙胺鹽酸鹽是烯丙胺和氯化氫形成的鹽，化學式為C3H8NCl。它可用於聚烯丙胺或聚烯丙胺鹽酸鹽的合成。[1]
| 烯丙胺鹽酸鹽 | |
|---|---|
| |
| 識別 | |
| CAS號 | 10017-11-5 
|
| 性質 | |
| 化學式 | C3H8ClN |
| 摩爾質量 | 93.56 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
製備及反應 編輯
烯丙胺鹽酸鹽可由烯丙胺和鹽酸在5 °C反應得到，在60 °C可整去大部分溶劑，然後在−80 °C凍干，得到固體。[2]N-Boc-烯丙胺和氯化氫反應，也能得到烯丙胺鹽酸鹽。[3]N,N-二(三甲基矽基)烯丙胺和鹽酸反應，也能得到該產物。[4]
它在含次磷酸的氫碘酸中煮沸反應，可以得到2-碘丙胺氫碘酸鹽。這一反應在常溫下不會發生。[5]它和氰酸鉀在水中加熱反應，可以得到烯丙基脲。[6]它和硫脲在苯甲醚中於180 °C反應，可以得到烯丙基異硫氰酸酯。[7]
參考文獻 編輯
- ^ Hiroaki Oie, Atsushi Sudo, Takeshi Endo. Synthesis of polymers bearing 1,3-benzoxazine moiety in the side chains from poly(allylamine) and their crosslinking behaviors. Journal of Polymer Science Part A: Polymer Chemistry. 2011-07-15, 49 (14): 3174–3183 [2022-05-02]. doi:10.1002/pola.24754. （原始內容存檔於2022-05-02） （英語）.
- ^ H. Iván Meléndez-Ortiz, Bertha Puente-Urbina, Griselda Castruita-de León, Jesus Alfonso Mercado-Silva, Esmeralda Saucedo-Salazar, Luis Alfonso García-Cerda. Covalent attachment of poly(allylamine hydrochloride) onto ordered silica foams. Journal of Porous Materials. 2020-06, 27 (3): 929–937 [2022-05-02]. ISSN 1380-2224. doi:10.1007/s10934-020-00870-8 （英語）.
- ^ Rik H. Verschueren, Philippe Gilles, Seger Van Mileghem, Wim M. De Borggraeve. Solvent-free N -Boc deprotection by ex situ generation of hydrogen chloride gas. Organic & Biomolecular Chemistry. 2021, 19 (26): 5782–5787 [2022-05-02]. ISSN 1477-0520. doi:10.1039/D1OB00728A （英語）.
- ^ Bestmann, Hans Juergen; Woelfel, Gerhard. Simple synthesis of primary amines via their N,N-bis(trimethylsilyl) derivatives. Chemische Berichte, 1984. 117 (3): 1250-1254. ISSN 0009-2940.
- ^ Eugenia S. Vasileiadou, Xinyi Jiang, Mikaël Kepenekian, Jacky Even, Michael C. De Siena, Vladislav V. Klepov, Daniel Friedrich, Ioannis Spanopoulos, Qing Tu, Imra S. Tajuddin, Emily A. Weiss, Mercouri G. Kanatzidis. Thick-Layer Lead Iodide Perovskites with Bifunctional Organic Spacers Allylammonium and Iodopropylammonium Exhibiting Trap-State Emission. Journal of the American Chemical Society. 2022-04-13, 144 (14): 6390–6409 [2022-05-02]. ISSN 0002-7863. doi:10.1021/jacs.2c00571. （原始內容存檔於2022-05-02） （英語）.
- ^ Ya Gao, Jinshan Xie, Ruotian Tang, Kaiyin Yang, Yahan Zhang, Lixia Chen, Hua Li. Identification of a pyrimidinetrione derivative as the potent DprE1 inhibitor by structure-based virtual ligand screening. Bioorganic Chemistry. 2019-04, 85: 168–178 [2022-05-02]. doi:10.1016/j.bioorg.2018.12.018 （英語）.
- ^ Shinohata, Masaaki; Kosugi, Yuji; Miyake, Nobuhisa. Method for preparation of isothiocyanates and storing the intermediates thiocarbamates. 2014 WO 2014136690 A1.