(環庚三烯基)(環戊二烯基)六氟磷酸錳 編輯

(環庚三烯基)(環戊二烯基)六氟磷酸錳是一種有機錳化合物,化學式為C12H12MnPF6。它可由(環庚三烯)(環戊二烯基)錳和三苯基六氟磷酸碳反應製得。[1]它可以通過丙酮-乙醇或丙酮-乙醚重結晶。[2]它的氧化電位為0.70 V,還原電位為−1.61 V。[3]

(環庚三烯基)(環戊二烯基)六氟磷酸錳
識別
CAS號 52308-73-3  checkY
性質
化學式 C12H12F6MnP
摩爾質量 356.13 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ P.L. Pauson; J.A. Segal (1973). Complete photochemical carbonyl substitution in cyclopentadienyltricarbonylmanganese. Journal of Organometallic Chemistry, 63. C13-C14. doi:10.1016/s0022-328x(73)80006-3.
  2. ^ Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. doi:10.1039/DT9750002387.
  3. ^ Reinhard Basse; et al. Cationic Cycloheptatrienyl Cyclopentadienyl Manganese Sandwich Complexes: Tromancenium Explored with High-Power LED Photosynthesis. Organometallics 2021, 40, 15, 2736–2749. doi:10.1021/acs.organomet.1c00376.