(环庚三烯基)(环戊二烯基)六氟磷酸锰

(环庚三烯基)(环戊二烯基)六氟磷酸锰是一种有机锰化合物,化学式为C12H12MnPF6。它可由(环庚三烯)(环戊二烯基)锰和三苯基六氟磷酸碳反应制得。[1]它可以通过丙酮-乙醇或丙酮-乙醚重结晶。[2]它的氧化电位为0.70 V,还原电位为−1.61 V。[3]

(环庚三烯基)(环戊二烯基)六氟磷酸锰
识别
CAS号 52308-73-3  checkY
性质
化学式 C12H12F6MnP
摩尔质量 356.13 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ P.L. Pauson; J.A. Segal (1973). Complete photochemical carbonyl substitution in cyclopentadienyltricarbonylmanganese. Journal of Organometallic Chemistry, 63. C13-C14. doi:10.1016/s0022-328x(73)80006-3.
  2. ^ Peter L. Pauson and John A. Segal. (η-Cycloheptatriene)- and (η-cycloheptatrienylium)-(η-cyclopentadienyl)manganese. Formation of cyclic triene complexes by photochemical displacement of three carbonyl groups from tricarbonyl-(η-cyclopentadienyl)manganese. J. Chem. Soc., Dalton Trans., 1975, 2387-2392. doi:10.1039/DT9750002387.
  3. ^ Reinhard Basse; et al. Cationic Cycloheptatrienyl Cyclopentadienyl Manganese Sandwich Complexes: Tromancenium Explored with High-Power LED Photosynthesis. Organometallics 2021, 40, 15, 2736–2749. doi:10.1021/acs.organomet.1c00376.