3-乙基戊醛
3-乙基戊醛是一種有機化合物,化學式為C7H14O。它可由4-乙基戊醇和吡啶氯鉻酸鹽的氧化反應製得[2],或通過3-亞甲基戊烷在乙酰丙酮二羰基銠的催化下的羰基化反應得到。[3]在催化下,它可以和硝基甲烷發生亨利反應,生成4-乙基-1-硝基-2-己醇。[4]
3-乙基戊醛 | |
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別名 | 3,3-二乙基丙醛 |
識別 | |
CAS號 | 39992-52-4 ![]() |
性質 | |
化學式 | C7H14O |
摩爾質量 | 114.19 g·mol−1 |
沸點 | 50—51 °C(323—324 K)(20 torr)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
編輯- ^ Homer. Adkins, George. Krsek. Hydroformylation of Unsaturated Compounds with a Cobalt Carbonyl Catalyst. Journal of the American Chemical Society. 1949-09, 71 (9): 3051–3055 [2022-03-07]. ISSN 0002-7863. doi:10.1021/ja01177a032. (原始內容存檔於2022-03-07) (英語).
- ^ Min Ting Liu, Jianghai Ho, Jason Karl Liu, Radhanath Purakait, Uriel N. Morzan, Lucky Ahmed, Victor S. Batista, Hiroaki Matsunami, Kevin Ryan. Carbon chain shape selectivity by the mouse olfactory receptor OR-I7. Organic & Biomolecular Chemistry. 2018, 16 (14): 2541–2548 [2022-03-07]. ISSN 1477-0520. PMC 6067823 . PMID 29569669. doi:10.1039/C8OB00205C (英語).
- ^ Josephine Eshon, Floriana Foarta, Clark R. Landis, Jennifer M. Schomaker. α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation. The Journal of Organic Chemistry. 2018-09-07, 83 (17): 10207–10220 [2022-03-07]. ISSN 0022-3263. PMC 6816342 . PMID 30070109. doi:10.1021/acs.joc.8b01431. (原始內容存檔於2022-03-07) (英語).
- ^ E. Chinnaraja, R. Arunachalam, P. S. Subramanian. Enantio- and Diastereoselective Synthesis of β-Nitroalcohol via Henry Reaction Catalyzed by Cu(II), Ni(II), Zn(II) Complexes of Chiral BINIM Ligands. ChemistrySelect. 2016-10-01, 1 (16): 5331–5338 [2022-03-07]. doi:10.1002/slct.201601186 (英語).