3-乙基戊醛
3-乙基戊醛是一种有机化合物，化学式为C7H14O。它可由4-乙基戊醇和吡啶氯铬酸盐的氧化反应制得[2]，或通过3-亚甲基戊烷在乙酰丙酮二羰基铑的催化下的羰基化反应得到。[3]在催化下，它可以和硝基甲烷发生亨利反应，生成4-乙基-1-硝基-2-己醇。[4]
| 3-乙基戊醛 | |
|---|---|
| |
| 别名 | 3,3-二乙基丙醛 |
| 识别 | |
| CAS号 | 39992-52-4 
|
| 性质 | |
| 化学式 | C7H14O |
| 摩尔质量 | 114.19 g·mol−1 |
| 沸点 | 50—51 °C（323—324 K）（20 torr）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Homer. Adkins, George. Krsek. Hydroformylation of Unsaturated Compounds with a Cobalt Carbonyl Catalyst. Journal of the American Chemical Society. 1949-09, 71 (9): 3051–3055 [2022-03-07]. ISSN 0002-7863. doi:10.1021/ja01177a032. （原始内容存档于2022-03-07） （英语）.
- ^ Min Ting Liu, Jianghai Ho, Jason Karl Liu, Radhanath Purakait, Uriel N. Morzan, Lucky Ahmed, Victor S. Batista, Hiroaki Matsunami, Kevin Ryan. Carbon chain shape selectivity by the mouse olfactory receptor OR-I7. Organic & Biomolecular Chemistry. 2018, 16 (14): 2541–2548 [2022-03-07]. ISSN 1477-0520. PMC 6067823
. PMID 29569669. doi:10.1039/C8OB00205C （英语）.
- ^ Josephine Eshon, Floriana Foarta, Clark R. Landis, Jennifer M. Schomaker. α-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation. The Journal of Organic Chemistry. 2018-09-07, 83 (17): 10207–10220 [2022-03-07]. ISSN 0022-3263. PMC 6816342 . PMID 30070109. doi:10.1021/acs.joc.8b01431. （原始内容存档于2022-03-07） （英语）.
- ^ E. Chinnaraja, R. Arunachalam, P. S. Subramanian. Enantio- and Diastereoselective Synthesis of β-Nitroalcohol via Henry Reaction Catalyzed by Cu(II), Ni(II), Zn(II) Complexes of Chiral BINIM Ligands. ChemistrySelect. 2016-10-01, 1 (16): 5331–5338 [2022-03-07]. doi:10.1002/slct.201601186 （英语）.
