二(二苯乙烯二硫醇)鎳

二(二苯乙烯二硫醇)鎳
別名	二[1,2-二苯基-1,2-乙烯二硫醇]鎳
識別
CAS號	28984-20-5
PubChem	5374634
ChemSpider	44211332
SMILES	C1=CC=C(C=C1)/C(=C(/[S-])\C2=CC=CC=C2)/[S-].C1=CC=C(C=C1)/C(=C(/[S-])\C2=CC=CC=C2)/[S-].[Ni];
性質
化學式	C28H20NiS4
摩爾質量	543.41 g·mol−1
外觀	黑綠色固體
密度	1.466 g/cm3
熔點	260 °C（533 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

二(二苯乙烯二硫醇)鎳是一種配位化合物，化學式為Ni(S₂C₂Ph₂)₂（其中Ph為苯基）。它是黑色固體，在甲苯中形成綠色溶液。它是二(烯烴二硫醇)類配體（Ni(S₂C₂R₂)₂，R為烴基或芳基）的一員，這類配體屬於noninnocent配體。^[1]該分子骨架中C-S和C-C鍵的鍵長分別為1.71和1.39 Å，長度介於單雙鍵之間。^[2]

該配合物可由二苯基乙炔和硫化鎳反應製得。^[3]其它製法包括鎳鹽和硫化苯偶姻的反應。該配合物和其它配體反應，得到單(烯烴二硫醇)配合物Ni(S₂C₂Ph₂)L₂。^[4]

參考文獻

^ Karlin, K. D.; Stiefel, E. I., Eds. 「Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis, Properties, and Applications」 Wiley-Interscience: New York, 2003. ISBN 0-471-37829-1
^ Miao, Qingqing; Gao, Junxiong; Wang, Zeqing; Yu, Hang; Luo, Yi; Ma, Tingli. Syntheses and Characterization of Several Nickel Bis(dithiolene) Complexes with Strong and Broad Near-IR Absorption. Inorganica Chimica Acta. 2011, 376: 619–627. doi:10.1016/j.ica.2011.07.046.
^ Schrauzer, G. N.; Mayweg, V. Reaction of Diphenylacetylene with Nickel Sulfides. Journal of the American Chemical Society. 1962, 84 (16): 3221. doi:10.1021/ja00875a061.
^ Obanda, Antony; Martinez, Kristina; Schmehl, Russell H.; Mague, Joel T.; Rubtsov, Igor V.; MacMillan, Samantha N.; Lancaster, Kyle M.; Sproules, Stephen; Donahue, James P. Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni²⁺, Pd²⁺, Pt²⁺) to Afford New Heteroleptic Dithiolene Complexes (PDF). Inorganic Chemistry. 2017, 56 (17): 10257–10267 [2019-12-27]. PMID 28820242. doi:10.1021/acs.inorgchem.7b00971. （原始內容存檔 (PDF)於2019-04-26）.

[1] Karlin, K. D.; Stiefel, E. I., Eds. 「Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis, Properties, and Applications」 Wiley-Interscience: New York, 2003. ISBN 0-471-37829-1

[2] Miao, Qingqing; Gao, Junxiong; Wang, Zeqing; Yu, Hang; Luo, Yi; Ma, Tingli. Syntheses and Characterization of Several Nickel Bis(dithiolene) Complexes with Strong and Broad Near-IR Absorption. Inorganica Chimica Acta. 2011, 376: 619–627. doi:10.1016/j.ica.2011.07.046.

[3] Schrauzer, G. N.; Mayweg, V. Reaction of Diphenylacetylene with Nickel Sulfides. Journal of the American Chemical Society. 1962, 84 (16): 3221. doi:10.1021/ja00875a061.

[4] Obanda, Antony; Martinez, Kristina; Schmehl, Russell H.; Mague, Joel T.; Rubtsov, Igor V.; MacMillan, Samantha N.; Lancaster, Kyle M.; Sproules, Stephen; Donahue, James P. Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni²⁺, Pd²⁺, Pt²⁺) to Afford New Heteroleptic Dithiolene Complexes (PDF). Inorganic Chemistry. 2017, 56 (17): 10257–10267 [2019-12-27]. PMID 28820242. doi:10.1021/acs.inorgchem.7b00971. （原始內容存檔 (PDF)於2019-04-26）.

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