氟三碘甲烷
化合物
氟三碘甲烷是一种甲烷衍生化合物，化学式CFI3。[2][3][4]它可以在三氟碘甲烷的辐解中产生，产生机理源自于反应中生成的:CFI和I2或CF3I的反应。[5][6]它的生成热−ΔHfθ为−2 kcal·mol−1，而CI3X的氯代或溴代物的值要更负。[7]
| 氟三碘甲烷 | |
|---|---|
| |
| IUPAC名 Fluoro(triiodo)methane | |
| 别名 | Fluorotriiodomethane |
| 识别 | |
| CAS号 | 1495-49-4 
|
| PubChem | 23510639 |
| ChemSpider | 11570071 |
| SMILES |
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| InChI |
|
| InChIKey | GXKSSISYTXERRQ-UHFFFAOYSA-N |
| 性质 | |
| 化学式 | CFI3 |
| 摩尔质量 | 411.72 g·mol−1 |
| 密度 | 3.847±0.06 g·cm−3[1] |
| 沸点 | 204.5±8.0 °C[1] |
| 溶解性（水） | 0.04 g/100 mL[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-3-23]
- ^ fluorotriiodomethane. NIST. wtt-pro.nist.gov. [7 June 2017]. （原始内容存档于2020-12-12）.
- ^ fluorotriiodomethane. webbook.nist.gov. [7 June 2017]. （原始内容存档于2019-11-16）.
- ^ Gurvich, L. V.; Veyts, I. Thermodynamic Properties of Individual Substances: Elements and Compounds. CRC Press. September 1, 1990: 185 [2019-03-23]. ISBN 9780891165330. （原始内容存档于2019-09-02）.
- ^ Nozomi Nakayama, Elizabeth E. Ferrenz, Denise R. Ostling, Andrea S. Nichols, Janelle F. Faulk, Christopher R. Arumainayagam. Surface Chemistry and Radiation Chemistry of Trifluoroiodomethane (CF 3 I) on Mo(110). The Journal of Physical Chemistry B. 2004-4, 108 (13): 4080–4085 [2019-03-23]. ISSN 1520-6106. doi:10.1021/jp0310192. （原始内容存档于2021-02-19） （英语）.
- ^ Mahesh Rajappan, Lin L Zhu, Jizhou Wang, Graeme Gardner, Kevin Bu, Huiliang Mai, Madeleine Laupheimer, Yomay Shyur, Nuriesya S Abu Bakar, Samantha K Skinner-Hall, Christina Kim, Jaclyn M Haskins, Christopher R Arumainayagam. The role of low-energy electrons in the high-energy radiolysis of condensed CF 3 I. Journal of Physics: Condensed Matter. 2010-03-03, 22 (8): 084006 [2019-03-23]. ISSN 0953-8984. doi:10.1088/0953-8984/22/8/084006.
- ^ Maslov, P. G.; Maslov, Yu. P. Heats of formation of halogen derivatives of methane and ethylene. Khimiya i Tekhnologiya Topliv i Masel, 1958. 3 (10): 50-55, ISSN 0023-1169.
拓展阅读
编辑
- Sladkov, I. B.; Bogacheva, A. V. Critical parameters of mixed halides of carbon. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1991. 64 (11): 2435-2437. ISSN: 0044-4618.