环十三烷
环十三烷（Cyclotridecane）是13个碳的环烷烃，化学式为。它可以环十二酮和氰乙酸乙酯为原料经多步反应制得；[1]它也可以双环戊酮环己酮三过氧化物为原料反应得到。[2]
| 环十三烷 | |
|---|---|
| |
| IUPAC名 Cyclotridecane | |
| 识别 | |
| CAS号 | 295-02-3 
|
| PubChem | 136145 |
| ChemSpider | 119922 |
| SMILES |
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| InChI |
|
| InChIKey | UEVXKGPJXXDGCX-UHFFFAOYAD |
| 性质 | |
| 化学式 | C13H26 |
| 摩尔质量 | 182.35 g·mol−1 |
| 熔点 | 23.5 °C（297 K） |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考资料
编辑- ^ Matthias K. Diedrich; Frank-Gerrit Klärner. The Effect of Pressure on Cyclizations. The Ring-Size Dependent Reaction Volumes of the Cyclization of 1-Alkenes to Cycloalkanes. Experimental Measurement of Activation and Reaction Volumes of the Intramolecular Diels−Alder Reaction of 1,3,8-Nonatriene and 1,3,9-Decatriene. Temperature Dependence of Activation and Reaction Volumes. J. Am. Chem. Soc. 1998, 120, 25, 6212–6218. doi:10.1021/ja973936p.
- ^ Alexandra Seemann; Johannes Panten; Andreas Kirschning. Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties. J. Org. Chem. 2021, 86, 20, 13924–13933. doi:10.1021/acs.joc.1c00663